Catalytic access to ferrocenyl phosphines bearing both planar and central chirality – A kinetic resolution approach via catalytic asymmetric P(III)–C bond formation

Catalytic access to ferrocenyl phosphines bearing both planar and central chirality – A kinetic resolution approach via catalytic asymmetric P(III)–C bond formation

A series of enantioenriched ferrocenyl monophosphines imbued with both central and planar chirality were obtained catalytically (80–99% ee) via the kinetic resolution of 1,2-disubstituted planar chiral ferrocenyl enone racemates. The synthetic approach utilized a chiral palladacycle to facilitate th...

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Bibliographic Details
Main Authors: Abdul Sadeer, Kojima, Tadayuki, Ng, Jia Sheng, Gan, Kennard Jun Hao, Chew, Renta Jonathan, Li, Yongxin, Pullarkat, Sumod Appukuttan
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Asymmetric
Hydrophosphination
Online Access:https://hdl.handle.net/10356/154139

Internet

https://hdl.handle.net/10356/154139

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