Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics

Highly pure and well-dispersed yttria nanocrystalline powders were synthesized with a modified coprecipitation method that uses mixed ammonium hydroxide-carbonate solution as the precipitant and poly acrylic acid (PAA) as the dispersant. Comparing with the yttria powders synthesized using the same r...

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Main Authors: Ni, Meng, Wang, Jun, Ma, Jie, Yao, Bingqing, Ong, Boon Chong, Dong, Zhili, Tang, Dingyuan
Other Authors: School of Electrical and Electronic Engineering
Format: Journal Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/154368
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author Ni, Meng
Wang, Jun
Ma, Jie
Yao, Bingqing
Ong, Boon Chong
Dong, Zhili
Tang, Dingyuan
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Ni, Meng
Wang, Jun
Ma, Jie
Yao, Bingqing
Ong, Boon Chong
Dong, Zhili
Tang, Dingyuan
author_sort Ni, Meng
collection NTU
description Highly pure and well-dispersed yttria nanocrystalline powders were synthesized with a modified coprecipitation method that uses mixed ammonium hydroxide-carbonate solution as the precipitant and poly acrylic acid (PAA) as the dispersant. Comparing with the yttria powders synthesized using the same route but without PAA dispersant, the PAA-assisted powders exhibit lower level of agglomeration and better sinterability. Sintering trajectories of the powders with and without PAA dispersant were investigated. Y2O3 ceramics sintered with the PAA-assisted powders exhibited smaller grain size, homogeneous microstructure, and higher in-line optical transmittance. The result suggests that the polymer-assisted coprecipitation could be used to synthesize yttria nanopowders for fabricating high optical quality transparent ceramics.
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spelling ntu-10356/1543682021-12-28T02:03:30Z Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics Ni, Meng Wang, Jun Ma, Jie Yao, Bingqing Ong, Boon Chong Dong, Zhili Tang, Dingyuan School of Electrical and Electronic Engineering School of Materials Science and Engineering Engineering::Electrical and electronic engineering Coprecipitation Transparent Ceramics Highly pure and well-dispersed yttria nanocrystalline powders were synthesized with a modified coprecipitation method that uses mixed ammonium hydroxide-carbonate solution as the precipitant and poly acrylic acid (PAA) as the dispersant. Comparing with the yttria powders synthesized using the same route but without PAA dispersant, the PAA-assisted powders exhibit lower level of agglomeration and better sinterability. Sintering trajectories of the powders with and without PAA dispersant were investigated. Y2O3 ceramics sintered with the PAA-assisted powders exhibited smaller grain size, homogeneous microstructure, and higher in-line optical transmittance. The result suggests that the polymer-assisted coprecipitation could be used to synthesize yttria nanopowders for fabricating high optical quality transparent ceramics. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Accepted version The research is partially supported byMinister of Edu-cation (MOE) Singapore, under Grant No. 2018-T1-001-145, and A*Star AME IRG project (A1883c0003) and Pri-ority Academic Program Development of Jiangsu HigherEducation Institutions (PADP), National Natural ScienceFoundation of China (NSFC), Grant No.61875078. 2021-12-18T07:05:04Z 2021-12-18T07:05:04Z 2021 Journal Article Ni, M., Wang, J., Ma, J., Yao, B., Ong, B. C., Dong, Z. & Tang, D. (2021). Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics. Journal of the American Ceramic Society. https://dx.doi.org/10.1111/jace.18205 0002-7820 https://hdl.handle.net/10356/154368 10.1111/jace.18205 2-s2.0-85118999087 en A1883c003 2018-T1-001-145 Journal of the American Ceramic Society © The American Ceramic Society 2021. This is the author's version of the work. It is posted here by permission of The American Ceramic Society for personal use, not for redistribution. The definitive version was published in the Journal of the American Ceramic Society. https://doi.org/10.1111/jace.18205. application/pdf
spellingShingle Engineering::Electrical and electronic engineering
Coprecipitation
Transparent Ceramics
Ni, Meng
Wang, Jun
Ma, Jie
Yao, Bingqing
Ong, Boon Chong
Dong, Zhili
Tang, Dingyuan
Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title_full Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title_fullStr Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title_full_unstemmed Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title_short Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
title_sort synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics
topic Engineering::Electrical and electronic engineering
Coprecipitation
Transparent Ceramics
url https://hdl.handle.net/10356/154368
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