Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination
The solution-state isomers of the heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra.
| Main Authors: | , |
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| Format: | Journal Article |
| Language: | English |
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2021
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| Online Access: | https://hdl.handle.net/10356/154509 |
| _version_ | 1811692840305033216 |
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| author | Ng, Shi Hoe Leong, Weng Kee |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Ng, Shi Hoe Leong, Weng Kee |
| author_sort | Ng, Shi Hoe |
| collection | NTU |
| description | The solution-state isomers of the heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra. |
| first_indexed | 2024-10-01T06:42:10Z |
| format | Journal Article |
| id | ntu-10356/154509 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:42:10Z |
| publishDate | 2021 |
| record_format | dspace |
| spelling | ntu-10356/1545092021-12-23T08:41:17Z Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination Ng, Shi Hoe Leong, Weng Kee School of Physical and Mathematical Sciences Division of Chemistry & Biological Chemistry Science::Chemistry Osmium Ruthenium The solution-state isomers of the heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra. Ministry of Education (MOE) Nanyang Technological University This work was supported by Nanyang Technological University and the Ministry of Education (Research Grant No. RG 121/18). 2021-12-23T08:41:17Z 2021-12-23T08:41:17Z 2021 Journal Article Ng, S. H. & Leong, W. K. (2021). Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination. Inorganica Chimica Acta, 514, 119989-. https://dx.doi.org/10.1016/j.ica.2020.119989 0020-1693 https://hdl.handle.net/10356/154509 10.1016/j.ica.2020.119989 2-s2.0-85090408804 514 119989 en RG 121/18 Inorganica Chimica Acta © 2020 Elsevier B.V. All rights reserved. |
| spellingShingle | Science::Chemistry Osmium Ruthenium Ng, Shi Hoe Leong, Weng Kee Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title | Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title_full | Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title_fullStr | Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title_full_unstemmed | Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title_short | Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination |
| title_sort | isomers in the phosphine substituted heteronuclear cluster ruos µ h ₂ co ₁₂ pph₃ a re examination |
| topic | Science::Chemistry Osmium Ruthenium |
| url | https://hdl.handle.net/10356/154509 |
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