Metal organic framework (MOF) in aqueous energy devices

Aqueous energy devices are under the spotlight of current research due to their safety, low cost and ease of handling. Metal-organic frameworks (MOFs) and their derivatives have spurred extensive exploration as they provide a library of new electrode materials. The rich and structural flexibilities...

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Main Authors: Tan, Hua, Zhou, Yao, Qiao, Shi-Zhang, Fan, Hong Jin
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/154787
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author Tan, Hua
Zhou, Yao
Qiao, Shi-Zhang
Fan, Hong Jin
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tan, Hua
Zhou, Yao
Qiao, Shi-Zhang
Fan, Hong Jin
author_sort Tan, Hua
collection NTU
description Aqueous energy devices are under the spotlight of current research due to their safety, low cost and ease of handling. Metal-organic frameworks (MOFs) and their derivatives have spurred extensive exploration as they provide a library of new electrode materials. The rich and structural flexibilities (such as metal nodes, ligands, pore structure) endow MOFs and MOFs-derivatives with vast opportunities for various energy devices. In this review, we discuss the correlation between MOF structural parameters and electrochemical performance for aqueous energy devices in the scope of zinc-based batteries (Zn-ion, Zn-alkaline and Zn-air batteries), potassium-ion batteries and supercapacitors. For each energy device, the effect of determinative factors and structural modulating strategies of MOFs and derivatives are highlighted. Finally, we summarize the challenges and provide our perspective about MOFs and derivatives for future aqueous energy devices.
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spelling ntu-10356/1547872023-02-28T19:40:06Z Metal organic framework (MOF) in aqueous energy devices Tan, Hua Zhou, Yao Qiao, Shi-Zhang Fan, Hong Jin School of Physical and Mathematical Sciences Engineering::Materials::Energy materials Aqueous energy devices are under the spotlight of current research due to their safety, low cost and ease of handling. Metal-organic frameworks (MOFs) and their derivatives have spurred extensive exploration as they provide a library of new electrode materials. The rich and structural flexibilities (such as metal nodes, ligands, pore structure) endow MOFs and MOFs-derivatives with vast opportunities for various energy devices. In this review, we discuss the correlation between MOF structural parameters and electrochemical performance for aqueous energy devices in the scope of zinc-based batteries (Zn-ion, Zn-alkaline and Zn-air batteries), potassium-ion batteries and supercapacitors. For each energy device, the effect of determinative factors and structural modulating strategies of MOFs and derivatives are highlighted. Finally, we summarize the challenges and provide our perspective about MOFs and derivatives for future aqueous energy devices. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Accepted version We thank the financial support from Singapore Ministry of Education by AcRF Tier 2 grant (MOE2017-T2-1-073) and from Agency for Science, Technology, and Research (A*STAR), Singapore by AME Individual Research Grants (A1983c0026), and Guangdong Province Science and Technology Department (Project No. 2020A0505100014). 2022-01-10T03:12:33Z 2022-01-10T03:12:33Z 2021 Journal Article Tan, H., Zhou, Y., Qiao, S. & Fan, H. J. (2021). Metal organic framework (MOF) in aqueous energy devices. Materials Today, 48, 270-284. https://dx.doi.org/10.1016/j.mattod.2021.03.011 1369-7021 https://hdl.handle.net/10356/154787 10.1016/j.mattod.2021.03.011 2-s2.0-85104661526 48 270 284 en MOE2017-T2-1-073 A1983c0026 Materials Today © 2021 Elsevier Ltd. All rights reserved. This paper was published in Materials Today and is made available with permission of Elsevier Ltd. application/pdf
spellingShingle Engineering::Materials::Energy materials
Tan, Hua
Zhou, Yao
Qiao, Shi-Zhang
Fan, Hong Jin
Metal organic framework (MOF) in aqueous energy devices
title Metal organic framework (MOF) in aqueous energy devices
title_full Metal organic framework (MOF) in aqueous energy devices
title_fullStr Metal organic framework (MOF) in aqueous energy devices
title_full_unstemmed Metal organic framework (MOF) in aqueous energy devices
title_short Metal organic framework (MOF) in aqueous energy devices
title_sort metal organic framework mof in aqueous energy devices
topic Engineering::Materials::Energy materials
url https://hdl.handle.net/10356/154787
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AT zhouyao metalorganicframeworkmofinaqueousenergydevices
AT qiaoshizhang metalorganicframeworkmofinaqueousenergydevices
AT fanhongjin metalorganicframeworkmofinaqueousenergydevices