Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides

Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides

A concise protocol for anti-hydromagnesiation of aryl alkynes was established using 1 : 1 molar combination of sodium hydride (NaH) and magnesium iodide (MgI2) without the aid of any transition metal catalysts. The resulting alkenylmagnesium intermediates could be trapped with a series of electrophi...

Detaylı Bibliyografya
Asıl Yazarlar:	Wang, Bin, Ong, Derek Yiren, Li, Yihang, Pang, Jia Hao, Watanabe, Kohei, Takita, Ryo, Chiba, Shunsuke
Diğer Yazarlar:	School of Physical and Mathematical Sciences
Materyal Türü:	Journal Article
Dil:	English
Baskı/Yayın Bilgisi:	2022
Konular:	Science::Chemistry Catalysts Hydrides
Online Erişim:	https://hdl.handle.net/10356/154834

Benzer Materyaller

Generation of allylmagnesium reagents by hydromagnesiation of 2-Aryl-1,3-dienes
Yazar:: Li, Yihang, ve diğerleri
Baskı/Yayın Bilgisi: (2023)

Hydromagnesiation of 1,3-enynes by magnesium hydride for synthesis of tri- and tetra-substituted allenes
Yazar:: Wang, Bin, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
Yazar:: Tejo, Ciputra, ve diğerleri
Baskı/Yayın Bilgisi: (2019)

Synthetic organic reactions mediated by sodium hydride
Yazar:: Ong, Derek Yiren, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Diastereoselective hydroalkylation of aryl alkenes enabled by remote hydride transfer
Yazar:: Gandamana, Dhika Aditya, ve diğerleri
Baskı/Yayın Bilgisi: (2021)

Synthesis of α-alkynylnitrones via hydromagnesiation of 1,3-enynes with magnesium hydride
Yazar:: Li, Yihang, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Mechanistic insights on reduction of carboxamides by diisobutylaluminum hydride and sodium hydride−iodide composite
Yazar:: Ong, Derek Yiren, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Hydroalkylation of 1,1-diarylalkenes mediated by magnesium hydride in ethereal solvents
Yazar:: Chaisan, Nattawadee, ve diğerleri
Baskı/Yayın Bilgisi: (2024)

Hydride Reduction by a Sodium Hydride-Iodide Composite
Yazar:: Too, Pei Chui, ve diğerleri
Baskı/Yayın Bilgisi: (2017)

Hydromagnesiation of 1,3-enynes and 1,3-dienes by magnesium hydride
Yazar:: Li, Yihang
Baskı/Yayın Bilgisi: (2023)

Inorganic hydrides/
Yazar:: 384634 Shaw, B. L.
Baskı/Yayın Bilgisi: (1967)

Leaving group ability in nucleophilic aromatic amination by sodium hydride-lithium iodide composite
Yazar:: Pang, Jia Hao, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Understanding the origins of nucleophilic hydride reactivity of a sodium hydride-iodide composite
Yazar:: Hong, Zonghan, ve diğerleri
Baskı/Yayın Bilgisi: (2018)

Base-induced dehydrogenative and dearomative transformation of 1-naphthylmethylamines to 1,4-dihydronaphthalene-1-carbonitriles
Yazar:: Sekiguchi, Yoshiya, ve diğerleri
Baskı/Yayın Bilgisi: (2023)

Interception of enamine intermediates in reductive functionalization of lactams by sodium hydride: synthesis of 2-cyano-3-iodo piperidines and pyrrolidines
Yazar:: Chen, Jiahua, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Stabilization of low-valence transition metal towards advanced catalytic effects on the hydrogen storage performance of magnesium hydride
Yazar:: Jian Zhang, ve diğerleri
Baskı/Yayın Bilgisi: (2021-03-01)

Hydrides of boron and silicon/
Yazar:: 206407 Stock, Alfred Eduard
Baskı/Yayın Bilgisi: (1933)

Hydrogen materials science and chemistry of metal hydrides /
Yazar:: NATO Advanced Research Workshop on Hydrogen Materials Science and Chemistry of Metal Hydrides (1999 : Katisiveli, Ukraine), ve diğerleri
Baskı/Yayın Bilgisi: (2002)

Hydroalkylation of styrenes with benzylamines by potassium hydride
Yazar:: Pang, Jia Hao, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Hydrides for energy storage/
Yazar:: Andersen, A. F., ve diğerleri
Baskı/Yayın Bilgisi: (1978)

The solid-state chemistry of binary metal hydrides. /
Yazar:: 241487 Libowitz, George G.
Baskı/Yayın Bilgisi: (1965)

Unstable Metal Hydrides for Possible On-Board Hydrogen Storage
Yazar:: Zhijie Cao, ve diğerleri
Baskı/Yayın Bilgisi: (2024-05-01)

Unexpected formation of hydrides in heavy rare earth containing magnesium alloys
Yazar:: Yuanding Huang, ve diğerleri
Baskı/Yayın Bilgisi: (2016-09-01)

Controlled reduction of carboxamides to alcohols or amines by zinc hydrides
Yazar:: Ong, Derek Yiren, ve diğerleri
Baskı/Yayın Bilgisi: (2020)

Controlled reduction of nitriles by sodium hydride and zinc chloride
Yazar:: Ong, Derek Yiren, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Hydrogen Absorbing Material in Carbonaceous-Metal Hydride
Yazar:: Farid Mulana
Baskı/Yayın Bilgisi: (2006-06-01)

Hydrogen Absorbing Material in Carbonaceous-Metal Hydride
Yazar:: Farid Mulana
Baskı/Yayın Bilgisi: (2006-06-01)

Evaluation of the Zirconium Hydride Morphology at the Flaws in the CANDU Pressure Tube Using a Novel Metric
Yazar:: Alexandra Ion Jinga, ve diğerleri
Baskı/Yayın Bilgisi: (2025-01-01)

Controlled Hydrogen Loading of Magnesium Thin Films in KOH—Effects on the Hydride Nucleation and Growth Regimes
Yazar:: Giorgia Guardi, ve diğerleri
Baskı/Yayın Bilgisi: (2024-12-01)

Active catalytic species generated in situ in zirconia incorporated hydrogen storage material magnesium hydride
Yazar:: D. Pukazhselvan, ve diğerleri
Baskı/Yayın Bilgisi: (2022-03-01)

Advances in highly hydrided palladium
Yazar:: Qianru Wang, ve diğerleri
Baskı/Yayın Bilgisi: (2024-02-01)

Numerical Investigation of Dual Metal Hydride Bed Based Thermochemical Energy Storage System
Yazar:: Sumeet Kumar Dubey, ve diğerleri
Baskı/Yayın Bilgisi: (2025-02-01)

Catalytic mechanisms of nickel nanoparticles for the improved dehydriding kinetics of magnesium hydride
Yazar:: Shuaijun Ding, ve diğerleri
Baskı/Yayın Bilgisi: (2024-10-01)

Ovonic Ni-metal hydride batteries for electric vehicles /
Yazar:: Ovshinsky, S R

C2 amination of pyridine with primary amines mediated by sodium hydride in the presence of lithium iodide
Yazar:: Pang, Jia Hao, ve diğerleri
Baskı/Yayın Bilgisi: (2022)

Promoting catalysis in magnesium hydride for solid-state hydrogen storage through manipulating the elements of high entropy oxides
Yazar:: Li Wang, ve diğerleri
Baskı/Yayın Bilgisi: (2024-12-01)

Understanding the catalysis of chromium trioxide added magnesium hydride for hydrogen storage and Li ion battery applications
Yazar:: D. Pukazhselvan, ve diğerleri
Baskı/Yayın Bilgisi: (2024-03-01)

Simultaneous determination of trace concentrations of arsenic, antimony, bismuth, selenium and tellurium in aqueous solution by introduction of the gaseous hydrides into an inductively coupled plasma source for emission spectrometry : Part I. Preliminary studies /
Yazar:: Thompson, M.

Mg-based materials for hydrogen storage
Yazar:: Yuanyuan Shang, ve diğerleri
Baskı/Yayın Bilgisi: (2021-11-01)

High‐Temperature Superconductivity in Perovskite Hydride Below 10 GPa
Yazar:: Mingyang Du, ve diğerleri
Baskı/Yayın Bilgisi: (2024-11-01)