Open questions in boron species with globally 4n π systems

The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity

Bibliographic Details
Main Authors: Ota, Kei, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/154955
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author Ota, Kei
Kinjo, Rei
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ota, Kei
Kinjo, Rei
author_sort Ota, Kei
collection NTU
description The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity
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spelling ntu-10356/1549552023-02-28T20:06:53Z Open questions in boron species with globally 4n π systems Ota, Kei Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry Chemical Bonding Hückel Rule The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity Ministry of Education (MOE) Nanyang Technological University Published version The authors gratefully acknowledge financial support from Nanyang Technological University and The Singapore Ministry of Education (MOE2018-T2-2-048(S)). 2022-05-27T01:26:51Z 2022-05-27T01:26:51Z 2021 Journal Article Ota, K. & Kinjo, R. (2021). Open questions in boron species with globally 4n π systems. Communications Chemistry, 4(1), 105-. https://dx.doi.org/10.1038/s42004-021-00542-x 2399-3669 https://hdl.handle.net/10356/154955 10.1038/s42004-021-00542-x 2-s2.0-85109907031 1 4 105 en MOE2018-T2-2-048(S) Communications Chemistry © 2021 The Author(s). This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/ licenses/by/4.0/. application/pdf
spellingShingle Science::Chemistry
Chemical Bonding
Hückel Rule
Ota, Kei
Kinjo, Rei
Open questions in boron species with globally 4n π systems
title Open questions in boron species with globally 4n π systems
title_full Open questions in boron species with globally 4n π systems
title_fullStr Open questions in boron species with globally 4n π systems
title_full_unstemmed Open questions in boron species with globally 4n π systems
title_short Open questions in boron species with globally 4n π systems
title_sort open questions in boron species with globally 4n π systems
topic Science::Chemistry
Chemical Bonding
Hückel Rule
url https://hdl.handle.net/10356/154955
work_keys_str_mv AT otakei openquestionsinboronspecieswithglobally4npsystems
AT kinjorei openquestionsinboronspecieswithglobally4npsystems