Carbene-catalyzed atroposelective annulation and desymmetrization of urazoles
An NHC-catalyzed atroposelective reaction between ynals and urazoles is disclosed. The reaction establishes a chiral C-N axis via an atroposelective [3 + 2] annulation/desymmetrization process. Our reaction allows efficient access to axially chiral and heteroatom-rich urazole derivatives with potent...
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Bibliographic Details
| Main Authors: |
Jin, Jiamiao,
Huang, Xuan,
Xu, Jun,
Li, Tingting,
Peng, Xiaolin,
Zhu, Xun,
Zhang, Junmin,
Jin, Zhichao,
Chi, Robin Yonggui |
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| Other Authors: |
School of Physical and Mathematical Sciences |
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| Format: | Journal Article
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| Language: | English |
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| Published: |
2022
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| Subjects: | |
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| Online Access: | https://hdl.handle.net/10356/155071
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