Advanced thermoelectric for waste heat harvesting

High entropy engineering has been observed to be able to extend the limits of optimization in thermoelectric performance. This technique involves introducing different atomic species to manipulate the configurational entropy of a material, resulting in the formation of a high entropy alloy. In this...

Full description

Bibliographic Details
Main Author: Tan, Justin Jia Jun
Other Authors: Alex Yan Qingyu
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2022
Subjects:
Online Access:https://hdl.handle.net/10356/156297
_version_ 1811682110553980928
author Tan, Justin Jia Jun
author2 Alex Yan Qingyu
author_facet Alex Yan Qingyu
Tan, Justin Jia Jun
author_sort Tan, Justin Jia Jun
collection NTU
description High entropy engineering has been observed to be able to extend the limits of optimization in thermoelectric performance. This technique involves introducing different atomic species to manipulate the configurational entropy of a material, resulting in the formation of a high entropy alloy. In this study, pellets of AgSnSbSe1.5PbxTex+1.5 were synthesized at varying PbTe concentration to analyse the effects of the dopant concentration on the thermoelectric properties. Pellets were thermal annealed and sintered with spark plasma sintering (SPS) before the thermoelectric properties were measured using the ULVAC ZEM-3 machine and the laser flash analysis (LFA) method. The structure and morphology of the pellets were characterized with the Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). After measurements, the composition of AgSnSbSe1.5Te1.5 + 10 % PbTe had the most favourable modifications in terms of its electrical and thermal conductivity. From the temperature range of 423 – 773 K, it displayed a high average power factor and ZTave of ~8.6 µW·cm-1·K-2 and ~0.69 accordingly. A peak ZT of ~0.80 was measured at the temperature of 723 K.
first_indexed 2024-10-01T03:51:38Z
format Final Year Project (FYP)
id ntu-10356/156297
institution Nanyang Technological University
language English
last_indexed 2024-10-01T03:51:38Z
publishDate 2022
publisher Nanyang Technological University
record_format dspace
spelling ntu-10356/1562972022-04-11T13:07:50Z Advanced thermoelectric for waste heat harvesting Tan, Justin Jia Jun Alex Yan Qingyu School of Materials Science and Engineering AlexYan@ntu.edu.sg Engineering::Materials::Testing of materials Engineering::Materials::Metallic materials::Alloys Engineering::Materials::Material testing and characterization High entropy engineering has been observed to be able to extend the limits of optimization in thermoelectric performance. This technique involves introducing different atomic species to manipulate the configurational entropy of a material, resulting in the formation of a high entropy alloy. In this study, pellets of AgSnSbSe1.5PbxTex+1.5 were synthesized at varying PbTe concentration to analyse the effects of the dopant concentration on the thermoelectric properties. Pellets were thermal annealed and sintered with spark plasma sintering (SPS) before the thermoelectric properties were measured using the ULVAC ZEM-3 machine and the laser flash analysis (LFA) method. The structure and morphology of the pellets were characterized with the Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). After measurements, the composition of AgSnSbSe1.5Te1.5 + 10 % PbTe had the most favourable modifications in terms of its electrical and thermal conductivity. From the temperature range of 423 – 773 K, it displayed a high average power factor and ZTave of ~8.6 µW·cm-1·K-2 and ~0.69 accordingly. A peak ZT of ~0.80 was measured at the temperature of 723 K. Bachelor of Engineering (Materials Engineering) 2022-04-11T13:07:50Z 2022-04-11T13:07:50Z 2022 Final Year Project (FYP) Tan, J. J. J. (2022). Advanced thermoelectric for waste heat harvesting. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/156297 https://hdl.handle.net/10356/156297 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials::Testing of materials
Engineering::Materials::Metallic materials::Alloys
Engineering::Materials::Material testing and characterization
Tan, Justin Jia Jun
Advanced thermoelectric for waste heat harvesting
title Advanced thermoelectric for waste heat harvesting
title_full Advanced thermoelectric for waste heat harvesting
title_fullStr Advanced thermoelectric for waste heat harvesting
title_full_unstemmed Advanced thermoelectric for waste heat harvesting
title_short Advanced thermoelectric for waste heat harvesting
title_sort advanced thermoelectric for waste heat harvesting
topic Engineering::Materials::Testing of materials
Engineering::Materials::Metallic materials::Alloys
Engineering::Materials::Material testing and characterization
url https://hdl.handle.net/10356/156297
work_keys_str_mv AT tanjustinjiajun advancedthermoelectricforwasteheatharvesting