Amidinatoamidosilylene−Dibromodiborene
The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2022
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/157593 |
| _version_ | 1826110105652822016 |
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| author | Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| author_sort | Fan, Jun |
| collection | NTU |
| description | The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3). |
| first_indexed | 2024-10-01T02:29:13Z |
| format | Journal Article |
| id | ntu-10356/157593 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:29:13Z |
| publishDate | 2022 |
| record_format | dspace |
| spelling | ntu-10356/1575932023-02-28T20:06:58Z Amidinatoamidosilylene−Dibromodiborene Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai School of Physical and Mathematical Sciences Science::Chemistry Silicon Bromine Compounds The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3). Ministry of Education (MOE) National Research Foundation (NRF) Submitted/Accepted version C.-W.S. thanks the National Research Foundation Singapore, NRF-ANR (NRF2018-NRF-ANR026 Si-POP), and Ministry of Education Singapore, AcRF Tier 2 (MOE2019-T2-2-129), for financial support. M.-C.Y. and M.-D.S. acknowledge the National Center for High-Performance Computing of Taiwan for generous amounts of computing time and the Ministry of Science and Technology of Taiwan for financial support. 2022-05-15T07:29:14Z 2022-05-15T07:29:14Z 2021 Journal Article Fan, J., Yang, M., Su, M. & So, C. (2021). Amidinatoamidosilylene−Dibromodiborene. Inorganic Chemistry, 60(21), 16065-16069. https://dx.doi.org/10.1021/acs.inorgchem.1c02541 0020-1669 https://hdl.handle.net/10356/157593 10.1021/acs.inorgchem.1c02541 21 60 16065 16069 en NRF2018-NRF-ANR026 Si-POP MOE2019-T2-2-129 Inorganic Chemistry This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.1c02541. application/pdf |
| spellingShingle | Science::Chemistry Silicon Bromine Compounds Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai Amidinatoamidosilylene−Dibromodiborene |
| title | Amidinatoamidosilylene−Dibromodiborene |
| title_full | Amidinatoamidosilylene−Dibromodiborene |
| title_fullStr | Amidinatoamidosilylene−Dibromodiborene |
| title_full_unstemmed | Amidinatoamidosilylene−Dibromodiborene |
| title_short | Amidinatoamidosilylene−Dibromodiborene |
| title_sort | amidinatoamidosilylene dibromodiborene |
| topic | Science::Chemistry Silicon Bromine Compounds |
| url | https://hdl.handle.net/10356/157593 |
| work_keys_str_mv | AT fanjun amidinatoamidosilylenedibromodiborene AT yangmingchung amidinatoamidosilylenedibromodiborene AT sumingder amidinatoamidosilylenedibromodiborene AT socheukwai amidinatoamidosilylenedibromodiborene |