Rotation of a helical coordination polymer by mechanical grinding
Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2022
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/160878 |
| _version_ | 1826124098720235520 |
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| author | Rath, Bibhuti Bhusan Kole, Goutam Kumar Morris, Samuel Alexander Vittal, Jagadese J. |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Rath, Bibhuti Bhusan Kole, Goutam Kumar Morris, Samuel Alexander Vittal, Jagadese J. |
| author_sort | Rath, Bibhuti Bhusan |
| collection | NTU |
| description | Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield. |
| first_indexed | 2024-10-01T06:15:08Z |
| format | Journal Article |
| id | ntu-10356/160878 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:15:08Z |
| publishDate | 2022 |
| record_format | dspace |
| spelling | ntu-10356/1608782022-08-05T02:58:44Z Rotation of a helical coordination polymer by mechanical grinding Rath, Bibhuti Bhusan Kole, Goutam Kumar Morris, Samuel Alexander Vittal, Jagadese J. School of Materials Science and Engineering Science::Chemistry Metal-Complex Mechanochemistry Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield. Ministry of Education (MOE) This work was financially supported by the Ministry of Education, Singapore (Grant No. Tier 1 WBS R-143-000-A12-114 and R-143-000-B13-114). 2022-08-05T02:58:44Z 2022-08-05T02:58:44Z 2020 Journal Article Rath, B. B., Kole, G. K., Morris, S. A. & Vittal, J. J. (2020). Rotation of a helical coordination polymer by mechanical grinding. Chemical Communications, 56(46), 6289-6292. https://dx.doi.org/10.1039/D0CC02158J 1359-7345 https://hdl.handle.net/10356/160878 10.1039/D0CC02158J 46 56 6289 6292 en WBS R-143-000-A12-114 R-143-000-B13-114 Chemical Communications © 2020 The Royal Society of Chemistry. All rights reserved. |
| spellingShingle | Science::Chemistry Metal-Complex Mechanochemistry Rath, Bibhuti Bhusan Kole, Goutam Kumar Morris, Samuel Alexander Vittal, Jagadese J. Rotation of a helical coordination polymer by mechanical grinding |
| title | Rotation of a helical coordination polymer by mechanical grinding |
| title_full | Rotation of a helical coordination polymer by mechanical grinding |
| title_fullStr | Rotation of a helical coordination polymer by mechanical grinding |
| title_full_unstemmed | Rotation of a helical coordination polymer by mechanical grinding |
| title_short | Rotation of a helical coordination polymer by mechanical grinding |
| title_sort | rotation of a helical coordination polymer by mechanical grinding |
| topic | Science::Chemistry Metal-Complex Mechanochemistry |
| url | https://hdl.handle.net/10356/160878 |
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