Gold modified polyaniline nanowire electrode arrays

A thin film of polycarbonate with numerous cylindrical nanopores was used as a template for growing polyaniline (PANI) nanowire arrays. A gold layer was initially sputtered at the polycarbonate template (PCT) with pore-diameter of 100 nm to form a conductive substrate. Within the nanopores, the PANI...

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Main Author: Choo, Winston Cai Min
Other Authors: Liu Erjia
Format: Final Year Project (FYP)
Language:English
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10356/16131
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author Choo, Winston Cai Min
author2 Liu Erjia
author_facet Liu Erjia
Choo, Winston Cai Min
author_sort Choo, Winston Cai Min
collection NTU
description A thin film of polycarbonate with numerous cylindrical nanopores was used as a template for growing polyaniline (PANI) nanowire arrays. A gold layer was initially sputtered at the polycarbonate template (PCT) with pore-diameter of 100 nm to form a conductive substrate. Within the nanopores, the PANI nanowires were electrochemically deposited from a diluted sulfuric acid solution containing aniline monomer, which was done using cyclic voltammetry (CV). The PANI nanowire arrays electrode was used successfully for the voltammetric determination of heavy metal, lead (Pb) in a 0.1 M acetate buffer solution of pH 5.3. Square wave anodic stripping voltammetry (SWASV) was used in the investigation of the trace of Pb(II) ions. Factors and varying stripping parameters were investigated and an optimized analytical procedure for the SWASV was developed. The results showed that the PANI nanowire arrays were significant enough to detect the tested metal ions. The technology of polymeric nanowires has shown its potential to positively impact analytical application in the testing of water quality.
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spelling ntu-10356/161312023-03-04T19:22:18Z Gold modified polyaniline nanowire electrode arrays Choo, Winston Cai Min Liu Erjia School of Mechanical and Aerospace Engineering DRNTU::Engineering::Nanotechnology A thin film of polycarbonate with numerous cylindrical nanopores was used as a template for growing polyaniline (PANI) nanowire arrays. A gold layer was initially sputtered at the polycarbonate template (PCT) with pore-diameter of 100 nm to form a conductive substrate. Within the nanopores, the PANI nanowires were electrochemically deposited from a diluted sulfuric acid solution containing aniline monomer, which was done using cyclic voltammetry (CV). The PANI nanowire arrays electrode was used successfully for the voltammetric determination of heavy metal, lead (Pb) in a 0.1 M acetate buffer solution of pH 5.3. Square wave anodic stripping voltammetry (SWASV) was used in the investigation of the trace of Pb(II) ions. Factors and varying stripping parameters were investigated and an optimized analytical procedure for the SWASV was developed. The results showed that the PANI nanowire arrays were significant enough to detect the tested metal ions. The technology of polymeric nanowires has shown its potential to positively impact analytical application in the testing of water quality. Bachelor of Engineering (Mechanical Engineering) 2009-05-21T06:24:52Z 2009-05-21T06:24:52Z 2009 2009 Final Year Project (FYP) http://hdl.handle.net/10356/16131 en Nanyang Technological University 94 p. application/pdf
spellingShingle DRNTU::Engineering::Nanotechnology
Choo, Winston Cai Min
Gold modified polyaniline nanowire electrode arrays
title Gold modified polyaniline nanowire electrode arrays
title_full Gold modified polyaniline nanowire electrode arrays
title_fullStr Gold modified polyaniline nanowire electrode arrays
title_full_unstemmed Gold modified polyaniline nanowire electrode arrays
title_short Gold modified polyaniline nanowire electrode arrays
title_sort gold modified polyaniline nanowire electrode arrays
topic DRNTU::Engineering::Nanotechnology
url http://hdl.handle.net/10356/16131
work_keys_str_mv AT choowinstoncaimin goldmodifiedpolyanilinenanowireelectrodearrays