Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?

Since the phase-out of traditional halogenated flame retardants (HFRs), interests of research are gradually being shifted to organophosphate flame retardants (OPFRs), and this can be reflected by the increasing number of publications on OPFRs year by year. Here, an extensive survey is conducted in a...

Full description

Bibliographic Details
Main Authors: Huang, Jianan, Ye, Langjie, Fang, Mingliang, Su, Guanyong
Other Authors: School of Civil and Environmental Engineering
Format: Journal Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/161754
_version_ 1826112024288952320
author Huang, Jianan
Ye, Langjie
Fang, Mingliang
Su, Guanyong
author2 School of Civil and Environmental Engineering
author_facet School of Civil and Environmental Engineering
Huang, Jianan
Ye, Langjie
Fang, Mingliang
Su, Guanyong
author_sort Huang, Jianan
collection NTU
description Since the phase-out of traditional halogenated flame retardants (HFRs), interests of research are gradually being shifted to organophosphate flame retardants (OPFRs), and this can be reflected by the increasing number of publications on OPFRs year by year. Here, an extensive survey is conducted in an attempt to generate a list of OPFRs that are being produced in factories, and to investigate the annual production volume (APV). This survey suggests that at least n = 56 OPFR monomers and n = 62 OPFR mixtures are being currently produced in 367 factories around the world, and 201 out of them are in Mainland China. APV of OPFRs was estimated as 598,422 metric tons, and this number could be underestimated due to the limitation of available information. We also notice that current researches are confined to a limited number of OPFRs, especially for OP esters (OPEs), and other OPFRs with different structures from OPEs has been rarely studied. Based on all the collected datasets, we provide five recommendations for how to proceed with future research to more comprehensively understand the currently-produced OPFRs in the environment.
first_indexed 2024-10-01T03:00:10Z
format Journal Article
id ntu-10356/161754
institution Nanyang Technological University
language English
last_indexed 2024-10-01T03:00:10Z
publishDate 2022
record_format dspace
spelling ntu-10356/1617542022-09-19T04:55:13Z Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled? Huang, Jianan Ye, Langjie Fang, Mingliang Su, Guanyong School of Civil and Environmental Engineering Engineering::Civil engineering Organophosphate Fame Retardants Organophosphate Esters Since the phase-out of traditional halogenated flame retardants (HFRs), interests of research are gradually being shifted to organophosphate flame retardants (OPFRs), and this can be reflected by the increasing number of publications on OPFRs year by year. Here, an extensive survey is conducted in an attempt to generate a list of OPFRs that are being produced in factories, and to investigate the annual production volume (APV). This survey suggests that at least n = 56 OPFR monomers and n = 62 OPFR mixtures are being currently produced in 367 factories around the world, and 201 out of them are in Mainland China. APV of OPFRs was estimated as 598,422 metric tons, and this number could be underestimated due to the limitation of available information. We also notice that current researches are confined to a limited number of OPFRs, especially for OP esters (OPEs), and other OPFRs with different structures from OPEs has been rarely studied. Based on all the collected datasets, we provide five recommendations for how to proceed with future research to more comprehensively understand the currently-produced OPFRs in the environment. This research was supported by the National Natural Science Foundation of China (Grant 21976088), and the Fundamental Research Funds for the Central Universities (Grant No. 30919011101). 2022-09-19T04:55:13Z 2022-09-19T04:55:13Z 2022 Journal Article Huang, J., Ye, L., Fang, M. & Su, G. (2022). Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?. Bulletin of Environmental Contamination and Toxicology, 108(5), 809-818. https://dx.doi.org/10.1007/s00128-021-03454-7 0007-4861 https://hdl.handle.net/10356/161754 10.1007/s00128-021-03454-7 35080673 2-s2.0-85123703079 5 108 809 818 en Bulletin of Environmental Contamination and Toxicology © 2022 The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. All rights reserved.
spellingShingle Engineering::Civil engineering
Organophosphate Fame Retardants
Organophosphate Esters
Huang, Jianan
Ye, Langjie
Fang, Mingliang
Su, Guanyong
Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title_full Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title_fullStr Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title_full_unstemmed Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title_short Industrial production of organophosphate flame retardants (OPFRs): big knowledge gaps need to be filled?
title_sort industrial production of organophosphate flame retardants opfrs big knowledge gaps need to be filled
topic Engineering::Civil engineering
Organophosphate Fame Retardants
Organophosphate Esters
url https://hdl.handle.net/10356/161754
work_keys_str_mv AT huangjianan industrialproductionoforganophosphateflameretardantsopfrsbigknowledgegapsneedtobefilled
AT yelangjie industrialproductionoforganophosphateflameretardantsopfrsbigknowledgegapsneedtobefilled
AT fangmingliang industrialproductionoforganophosphateflameretardantsopfrsbigknowledgegapsneedtobefilled
AT suguanyong industrialproductionoforganophosphateflameretardantsopfrsbigknowledgegapsneedtobefilled