A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural
The selective hydrogenation of 5-hydroxymethylfurfural (HMF) has been of great interest to many scientists and researchers. However, conventional hydrogenation inevitably requires the use of gaseous hydrogen as a reducing agent, which is detrimental to its storage and transport. In this regard, othe...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Language: | English |
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2022
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| Online Access: | https://hdl.handle.net/10356/162293 |
| _version_ | 1811682378309959680 |
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| author | He, Yima Deng, Limin Lee, Yuyou Li, Kaixin Lee, Jong-Min |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering He, Yima Deng, Limin Lee, Yuyou Li, Kaixin Lee, Jong-Min |
| author_sort | He, Yima |
| collection | NTU |
| description | The selective hydrogenation of 5-hydroxymethylfurfural (HMF) has been of great interest to many scientists and researchers. However, conventional hydrogenation inevitably requires the use of gaseous hydrogen as a reducing agent, which is detrimental to its storage and transport. In this regard, other economical and environmentally friendly strategies, such as catalytic transfer hydrogenation/hydrogenolysis without external molecular H2 , become more and more attractive. This Review provides the status and insight into the current research of hydrogenating HMF to high-value chemicals, using formic acid, alcohols, polymethylhydrosiloxane, water, and sodium borohydride as hydrogen donors and explains the hydrogenation mechanisms and the related hydrogenation characteristics of different hydrogen donors in the catalytic systems. |
| first_indexed | 2024-10-01T03:55:53Z |
| format | Journal Article |
| id | ntu-10356/162293 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:55:53Z |
| publishDate | 2022 |
| record_format | dspace |
| spelling | ntu-10356/1622932022-10-12T02:17:44Z A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural He, Yima Deng, Limin Lee, Yuyou Li, Kaixin Lee, Jong-Min School of Chemical and Biomedical Engineering Engineering::Chemical engineering Catalytic Transfer Hydrogenation Electrocatalytic Hydrogenation The selective hydrogenation of 5-hydroxymethylfurfural (HMF) has been of great interest to many scientists and researchers. However, conventional hydrogenation inevitably requires the use of gaseous hydrogen as a reducing agent, which is detrimental to its storage and transport. In this regard, other economical and environmentally friendly strategies, such as catalytic transfer hydrogenation/hydrogenolysis without external molecular H2 , become more and more attractive. This Review provides the status and insight into the current research of hydrogenating HMF to high-value chemicals, using formic acid, alcohols, polymethylhydrosiloxane, water, and sodium borohydride as hydrogen donors and explains the hydrogenation mechanisms and the related hydrogenation characteristics of different hydrogen donors in the catalytic systems. This work was financially supported by the Science and Technology Planning Project of Guangdong Province of China(2019A050510014)and the National Natural Science Foundation of China(22008037). 2022-10-12T02:17:44Z 2022-10-12T02:17:44Z 2022 Journal Article He, Y., Deng, L., Lee, Y., Li, K. & Lee, J. (2022). A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural. ChemSusChem, 15(13), e202200232-. https://dx.doi.org/10.1002/cssc.202200232 1864-5631 https://hdl.handle.net/10356/162293 10.1002/cssc.202200232 35244338 2-s2.0-85127282748 13 15 e202200232 en ChemSusChem © 2022 Wiley-VCH GmbH. All rights reserved. |
| spellingShingle | Engineering::Chemical engineering Catalytic Transfer Hydrogenation Electrocatalytic Hydrogenation He, Yima Deng, Limin Lee, Yuyou Li, Kaixin Lee, Jong-Min A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title | A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title_full | A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title_fullStr | A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title_full_unstemmed | A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title_short | A review on the critical role of H₂ donor in the selective hydrogenation of 5-hydroxymethylfurfural |
| title_sort | review on the critical role of h₂ donor in the selective hydrogenation of 5 hydroxymethylfurfural |
| topic | Engineering::Chemical engineering Catalytic Transfer Hydrogenation Electrocatalytic Hydrogenation |
| url | https://hdl.handle.net/10356/162293 |
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