Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage
The drastic need for development of power and electronic equipment has long been calling for energy storage materials that possess favorable energy and power densities simultaneously, yet neither capacitive nor battery-type materials can meet the aforementioned demand. By contrast, pseudocapacitive...
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Format: | Journal Article |
Language: | English |
Published: |
2022
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Online Access: | https://hdl.handle.net/10356/162297 |
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author | Gan, Zihan Yin, Junyi Xu, Xin Cheng, Yonghong Yu, Ting |
author2 | School of Physical and Mathematical Sciences |
author_facet | School of Physical and Mathematical Sciences Gan, Zihan Yin, Junyi Xu, Xin Cheng, Yonghong Yu, Ting |
author_sort | Gan, Zihan |
collection | NTU |
description | The drastic need for development of power and electronic equipment has long been calling for energy storage materials that possess favorable energy and power densities simultaneously, yet neither capacitive nor battery-type materials can meet the aforementioned demand. By contrast, pseudocapacitive materials store ions through redox reactions with charge/discharge rates comparable to those of capacitors, holding the promise of serving as electrode materials in advanced electrochemical energy storage (EES) devices. Therefore, it is of vital importance to enhance pseudocapacitive responses of energy storage materials to obtain excellent energy and power densities at the same time. In this Review, we first present basic concepts and characteristics about pseudocapacitive behaviors for better guidance on material design researches. Second, we discuss several important and effective material design measures for boosting pseudocapacitive responses of materials to improve rate capabilities, which mainly include downsizing, heterostructure engineering, adding atom and vacancy dopants, expanding interlayer distance, exposing active facets, and designing nanosheets. Finally, we outline possible developing trends in the rational design of pseudocapacitive materials and EES devices toward high-performance energy storage. |
first_indexed | 2024-10-01T07:10:36Z |
format | Journal Article |
id | ntu-10356/162297 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:10:36Z |
publishDate | 2022 |
record_format | dspace |
spelling | ntu-10356/1622972022-10-12T04:06:27Z Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage Gan, Zihan Yin, Junyi Xu, Xin Cheng, Yonghong Yu, Ting School of Physical and Mathematical Sciences Science::Physics Energy Storage Pseudocapacitive Materials The drastic need for development of power and electronic equipment has long been calling for energy storage materials that possess favorable energy and power densities simultaneously, yet neither capacitive nor battery-type materials can meet the aforementioned demand. By contrast, pseudocapacitive materials store ions through redox reactions with charge/discharge rates comparable to those of capacitors, holding the promise of serving as electrode materials in advanced electrochemical energy storage (EES) devices. Therefore, it is of vital importance to enhance pseudocapacitive responses of energy storage materials to obtain excellent energy and power densities at the same time. In this Review, we first present basic concepts and characteristics about pseudocapacitive behaviors for better guidance on material design researches. Second, we discuss several important and effective material design measures for boosting pseudocapacitive responses of materials to improve rate capabilities, which mainly include downsizing, heterostructure engineering, adding atom and vacancy dopants, expanding interlayer distance, exposing active facets, and designing nanosheets. Finally, we outline possible developing trends in the rational design of pseudocapacitive materials and EES devices toward high-performance energy storage. We thank the State Key Laboratory of Electrical Insulation and Power Equipment (EIPE21309), the Young Talent Recruiting Plans of Xi’an Jiaotong University (DQ6J012), and Fundamental Research Funds for the Central Universities (xtr042021008) for financial support. 2022-10-12T04:06:27Z 2022-10-12T04:06:27Z 2022 Journal Article Gan, Z., Yin, J., Xu, X., Cheng, Y. & Yu, T. (2022). Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage. ACS Nano, 16(4), 5131-5152. https://dx.doi.org/10.1021/acsnano.2c00557 1936-0851 https://hdl.handle.net/10356/162297 10.1021/acsnano.2c00557 35293209 2-s2.0-85127370114 4 16 5131 5152 en ACS Nano © 2022 American Chemical Society. All rights reserved. |
spellingShingle | Science::Physics Energy Storage Pseudocapacitive Materials Gan, Zihan Yin, Junyi Xu, Xin Cheng, Yonghong Yu, Ting Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title | Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title_full | Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title_fullStr | Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title_full_unstemmed | Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title_short | Nanostructure and advanced energy storage: elaborate material designs lead to high-rate pseudocapacitive ion storage |
title_sort | nanostructure and advanced energy storage elaborate material designs lead to high rate pseudocapacitive ion storage |
topic | Science::Physics Energy Storage Pseudocapacitive Materials |
url | https://hdl.handle.net/10356/162297 |
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