Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage

With the excessive consumption of non-renewable resources, the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system. In this aspect, metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorgan...

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Príomhchruthaitheoirí: Zhu, Jing, Chen, Xiaoyu, Thang, Ai Qin, Li, Fei-Long, Chen, Dong, Geng, Hongbo, Rui, Xianhong, Yan, Qingyu
Rannpháirtithe: School of Materials Science and Engineering
Formáid: Journal Article
Teanga:English
Foilsithe / Cruthaithe: 2022
Ábhair:
Rochtain ar líne:https://hdl.handle.net/10356/163798
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author Zhu, Jing
Chen, Xiaoyu
Thang, Ai Qin
Li, Fei-Long
Chen, Dong
Geng, Hongbo
Rui, Xianhong
Yan, Qingyu
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Zhu, Jing
Chen, Xiaoyu
Thang, Ai Qin
Li, Fei-Long
Chen, Dong
Geng, Hongbo
Rui, Xianhong
Yan, Qingyu
author_sort Zhu, Jing
collection NTU
description With the excessive consumption of non-renewable resources, the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system. In this aspect, metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorganic hybrid materials. MOFs have recently been gaining traction in energy-related fields. Owing to the coordination flexibility and multiple accessible oxidation states of vanadium ions or clusters, Vanadium-MOFs (VMOFs) possess unique structural characteristics and satisfactory electrochemical properties. Furthermore, V-MOFs derived materials also exhibit superior electrical conductivity and stability when used as electrocatalysts and electrode materials. This review summarizes the research progress of V-MOFs (inclusive of pristine V-MOFs, V/M-MOFs and POV-based MOFs) and their derivatives (vanadium oxides, carboncoated vanadium oxide, vanadium phosphate, vanadate, and other vanadium doped nanomaterials) in electrochemical energy conversion (water splitting, oxygen reduction reaction) and energy storage (supercapacitor, rechargeable battery). Future possibilities and challenges for V-MOFs and their derivatives in terms of design and synthesis are discussed. Lastly, their applications in energy-related fields are also highlighted.
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spelling ntu-10356/1637982023-07-14T16:06:24Z Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage Zhu, Jing Chen, Xiaoyu Thang, Ai Qin Li, Fei-Long Chen, Dong Geng, Hongbo Rui, Xianhong Yan, Qingyu School of Materials Science and Engineering Engineering::Materials::Energy materials Engineering::Materials::Functional materials Derivatives Electrocatalysis With the excessive consumption of non-renewable resources, the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system. In this aspect, metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorganic hybrid materials. MOFs have recently been gaining traction in energy-related fields. Owing to the coordination flexibility and multiple accessible oxidation states of vanadium ions or clusters, Vanadium-MOFs (VMOFs) possess unique structural characteristics and satisfactory electrochemical properties. Furthermore, V-MOFs derived materials also exhibit superior electrical conductivity and stability when used as electrocatalysts and electrode materials. This review summarizes the research progress of V-MOFs (inclusive of pristine V-MOFs, V/M-MOFs and POV-based MOFs) and their derivatives (vanadium oxides, carboncoated vanadium oxide, vanadium phosphate, vanadate, and other vanadium doped nanomaterials) in electrochemical energy conversion (water splitting, oxygen reduction reaction) and energy storage (supercapacitor, rechargeable battery). Future possibilities and challenges for V-MOFs and their derivatives in terms of design and synthesis are discussed. Lastly, their applications in energy-related fields are also highlighted. Ministry of Education (MOE) National Research Foundation (NRF) Published version The authors gratefully acknowledge the National Natural Science Foundation of China (Nos. 51972067, 22001021, 51802044, 51902062 and 51802043), Guangdong Natural Science Funds for Distinguished Young Scholar (No.2019B151502039), Natural Science Foundation of Jiangsu Province (No. BK20201048), Natural Science Research Project of Higher Education Institutions in Jiangsu Province (No. 20KJB150008), Singapore MOE AcRF Tier 1(No. 2020‐T1‐001‐031), the Open Fund of State Key Laboratory of Tea Plant Biology and Utilization (No.SKLTOF20190119), and the National Research Foundation of Singapore (NRF) Investigatorship (No. NRF2016NRF‐NRFI001‐22). 2022-12-19T04:44:12Z 2022-12-19T04:44:12Z 2022 Journal Article Zhu, J., Chen, X., Thang, A. Q., Li, F., Chen, D., Geng, H., Rui, X. & Yan, Q. (2022). Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage. SmartMat, 3(3), 384-416. https://dx.doi.org/10.1002/smm2.1091 2688-819X https://hdl.handle.net/10356/163798 10.1002/smm2.1091 3 3 384 416 en NRF2016NRF‐NRFI001‐22 2020‐T1‐001‐031 SmartMat © 2022 The Authors. SmartMat published by Tianjin University and John Wiley & Sons Australia, Ltd. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited application/pdf
spellingShingle Engineering::Materials::Energy materials
Engineering::Materials::Functional materials
Derivatives
Electrocatalysis
Zhu, Jing
Chen, Xiaoyu
Thang, Ai Qin
Li, Fei-Long
Chen, Dong
Geng, Hongbo
Rui, Xianhong
Yan, Qingyu
Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title_full Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title_fullStr Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title_full_unstemmed Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title_short Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
title_sort vanadium based metal organic frameworks and their derivatives for electrochemical energy conversion and storage
topic Engineering::Materials::Energy materials
Engineering::Materials::Functional materials
Derivatives
Electrocatalysis
url https://hdl.handle.net/10356/163798
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