Tailoring perovskites for solar cells and light emission applications

Perovskites have shown great potential for applications in solar cells and light emission. Recently, two-dimensional (2D) perovskites have started making waves in the research field. With their superior tunability and stability, they show great potential for a wide variety of applications. However,...

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Main Author: Nur Shahzani Binte Anwar
Other Authors: Shen Zexiang
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2022
Subjects:
Online Access:https://hdl.handle.net/10356/163844
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author Nur Shahzani Binte Anwar
author2 Shen Zexiang
author_facet Shen Zexiang
Nur Shahzani Binte Anwar
author_sort Nur Shahzani Binte Anwar
collection NTU
description Perovskites have shown great potential for applications in solar cells and light emission. Recently, two-dimensional (2D) perovskites have started making waves in the research field. With their superior tunability and stability, they show great potential for a wide variety of applications. However, their performance in photovoltaic and optoelectronic applications are mediocre. In this report, a 2D perovskite with a novel functionalised organic component is exposed to high pressures in hopes of improving its performance for both solar cell and light emission applications. It was found that the inorganic lattice was quite sensitive in pressure, experiencing contraction and distortion in pressures of less than 5 GPa. This caused obvious changes in optical properties at relatively low pressures applied. This is due to the soft organic cations being very bendable and hence flexible, allowing for room to withstand pressure and instead, causing the inorganic lattice to undergo the effects of compression more severely. However, although the pressure-treated sample retained most of it optical properties, it did not retain most of its structural properties. Only the ammonium constituents in the organic cation was retained. This implies that most of the changes in the perovskite crystal structure is irreversible, and that other bonds were actually responsible for the similar pressure-treated optical properties.
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spelling ntu-10356/1638442022-12-19T15:17:35Z Tailoring perovskites for solar cells and light emission applications Nur Shahzani Binte Anwar Shen Zexiang School of Materials Science and Engineering zexiang@ntu.edu.sg Engineering::Materials::Photonics and optoelectronics materials Perovskites have shown great potential for applications in solar cells and light emission. Recently, two-dimensional (2D) perovskites have started making waves in the research field. With their superior tunability and stability, they show great potential for a wide variety of applications. However, their performance in photovoltaic and optoelectronic applications are mediocre. In this report, a 2D perovskite with a novel functionalised organic component is exposed to high pressures in hopes of improving its performance for both solar cell and light emission applications. It was found that the inorganic lattice was quite sensitive in pressure, experiencing contraction and distortion in pressures of less than 5 GPa. This caused obvious changes in optical properties at relatively low pressures applied. This is due to the soft organic cations being very bendable and hence flexible, allowing for room to withstand pressure and instead, causing the inorganic lattice to undergo the effects of compression more severely. However, although the pressure-treated sample retained most of it optical properties, it did not retain most of its structural properties. Only the ammonium constituents in the organic cation was retained. This implies that most of the changes in the perovskite crystal structure is irreversible, and that other bonds were actually responsible for the similar pressure-treated optical properties. Bachelor of Engineering (Materials Engineering) 2022-12-19T15:17:35Z 2022-12-19T15:17:35Z 2022 Final Year Project (FYP) Nur Shahzani Binte Anwar (2022). Tailoring perovskites for solar cells and light emission applications. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/163844 https://hdl.handle.net/10356/163844 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials::Photonics and optoelectronics materials
Nur Shahzani Binte Anwar
Tailoring perovskites for solar cells and light emission applications
title Tailoring perovskites for solar cells and light emission applications
title_full Tailoring perovskites for solar cells and light emission applications
title_fullStr Tailoring perovskites for solar cells and light emission applications
title_full_unstemmed Tailoring perovskites for solar cells and light emission applications
title_short Tailoring perovskites for solar cells and light emission applications
title_sort tailoring perovskites for solar cells and light emission applications
topic Engineering::Materials::Photonics and optoelectronics materials
url https://hdl.handle.net/10356/163844
work_keys_str_mv AT nurshahzanibinteanwar tailoringperovskitesforsolarcellsandlightemissionapplications