Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)

Volatile organic compounds (VOCs) can lead to environmental pollution and threaten human health due to their toxic and carcinogenic nature. The emission of VOCs increases dramatically with the accelerated industrialization and economic growth. Adsorption is identified as one of the most promising re...

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Main Author: Shen, Yafei
Other Authors: Nanyang Environment and Water Research Institute
Format: Journal Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/164504
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author Shen, Yafei
author2 Nanyang Environment and Water Research Institute
author_facet Nanyang Environment and Water Research Institute
Shen, Yafei
author_sort Shen, Yafei
collection NTU
description Volatile organic compounds (VOCs) can lead to environmental pollution and threaten human health due to their toxic and carcinogenic nature. The emission of VOCs increases dramatically with the accelerated industrialization and economic growth. Adsorption is identified as one of the most promising recovery technologies owing to its cost-effectiveness, flexible operation, and low energy consumption. In particular, adsorption-based technologies have a high potential to recycle both adsorbents and adsorbates, typically to capture valuable aromatic VOCs from industrial exhaust. Porous materials such as carbon-based materials, zeolite-based materials, and organic polymers and their composites have been extensively developed for VOCs adsorption focusing in adsorption capacity, hydrophobic property, thermal stability and regenerability. Among them, porous carbons as VOCs adsorbents have attracted increasingly attention, because they can be regulated by tuning the pore structure for VOCs accessibility during the adsorption process. Moreover, porous carbons can adsorb target VOCs by controlling the pore structure and surface functional groups. Significantly, the pore size distribution of porous carbons mostly controls the VOCs sorption process. Micropores provide the main adsorption sites, while mesopores enhance the diffusion of VOCs. In this review, the adsorption mechanism of VOCs onto porous carbons was generally concluded. Porous carbons can be designed as a specific structure for adsorption of aromatic VOCs by controlling the pore structure, hydrophobic sites, π-electronic structure, and surface functional groups. Since there are limited review literatures on porous carbons derived from renewable resources for VOCs adsorption, this paper will provide an overview on the synthesis of porous carbons from biomass and other organic wastes for VOCs adsorption or integrated oxidation processes (e.g., photocatalysis, non-thermal plasma catalysis, chemical catalysis) under ambient conditions with the objective of guiding future works on the VOCs abatement technologies towards a sustainable direction.
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spelling ntu-10356/1645042023-01-30T04:07:50Z Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs) Shen, Yafei Nanyang Environment and Water Research Institute Residues and Resource Reclamation Centre Engineering::Environmental engineering Biomass Activation Volatile organic compounds (VOCs) can lead to environmental pollution and threaten human health due to their toxic and carcinogenic nature. The emission of VOCs increases dramatically with the accelerated industrialization and economic growth. Adsorption is identified as one of the most promising recovery technologies owing to its cost-effectiveness, flexible operation, and low energy consumption. In particular, adsorption-based technologies have a high potential to recycle both adsorbents and adsorbates, typically to capture valuable aromatic VOCs from industrial exhaust. Porous materials such as carbon-based materials, zeolite-based materials, and organic polymers and their composites have been extensively developed for VOCs adsorption focusing in adsorption capacity, hydrophobic property, thermal stability and regenerability. Among them, porous carbons as VOCs adsorbents have attracted increasingly attention, because they can be regulated by tuning the pore structure for VOCs accessibility during the adsorption process. Moreover, porous carbons can adsorb target VOCs by controlling the pore structure and surface functional groups. Significantly, the pore size distribution of porous carbons mostly controls the VOCs sorption process. Micropores provide the main adsorption sites, while mesopores enhance the diffusion of VOCs. In this review, the adsorption mechanism of VOCs onto porous carbons was generally concluded. Porous carbons can be designed as a specific structure for adsorption of aromatic VOCs by controlling the pore structure, hydrophobic sites, π-electronic structure, and surface functional groups. Since there are limited review literatures on porous carbons derived from renewable resources for VOCs adsorption, this paper will provide an overview on the synthesis of porous carbons from biomass and other organic wastes for VOCs adsorption or integrated oxidation processes (e.g., photocatalysis, non-thermal plasma catalysis, chemical catalysis) under ambient conditions with the objective of guiding future works on the VOCs abatement technologies towards a sustainable direction. This work is supported by the National Natural Science Foundation of China (Grant 21607079) and “333 talent” project of Jiangsu Province. 2023-01-30T04:07:50Z 2023-01-30T04:07:50Z 2023 Journal Article Shen, Y. (2023). Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs). Fuel, 336, 126801-. https://dx.doi.org/10.1016/j.fuel.2022.126801 0016-2361 https://hdl.handle.net/10356/164504 10.1016/j.fuel.2022.126801 2-s2.0-85142707256 336 126801 en Fuel © 2022 Elsevier Ltd. All rights reserved.
spellingShingle Engineering::Environmental engineering
Biomass
Activation
Shen, Yafei
Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title_full Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title_fullStr Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title_full_unstemmed Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title_short Biomass-derived porous carbons for sorption of Volatile organic compounds (VOCs)
title_sort biomass derived porous carbons for sorption of volatile organic compounds vocs
topic Engineering::Environmental engineering
Biomass
Activation
url https://hdl.handle.net/10356/164504
work_keys_str_mv AT shenyafei biomassderivedporouscarbonsforsorptionofvolatileorganiccompoundsvocs