A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications
The enhanced power density, long term cycling stability, and fast rate of operation, makes supercapacitors as desirable energy storage devices. Though metal oxides play a significant part in energy storage systems, Vanadium oxides have piqued the interest of electrochemists due to their multi-valenc...
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Format: | Journal Article |
Language: | English |
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2023
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Online Access: | https://hdl.handle.net/10356/164590 |
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author | Sutrave, Shivani Konda, Shireesha Velpula, Divya Volety, Sriram Ankith Ravula, Sugunakar Reddy Chidurala, Shilpa Chakra Tumma, Bala Narsaiah |
author2 | Energy Research Institute @ NTU (ERI@N) |
author_facet | Energy Research Institute @ NTU (ERI@N) Sutrave, Shivani Konda, Shireesha Velpula, Divya Volety, Sriram Ankith Ravula, Sugunakar Reddy Chidurala, Shilpa Chakra Tumma, Bala Narsaiah |
author_sort | Sutrave, Shivani |
collection | NTU |
description | The enhanced power density, long term cycling stability, and fast rate of operation, makes supercapacitors as desirable energy storage devices. Though metal oxides play a significant part in energy storage systems, Vanadium oxides have piqued the interest of electrochemists due to their multi-valency, potential window, unique layer structure, affordability, and plentiful availability. Vanadium pentoxide typically has relatively low specific capacitance due to its weak electrical conductivity and ionic diffusivity. However, these properties can be enhanced by encasing vanadium pentoxide in metal or carbonaceous materials, reducing it to the nanoscale, or changing its shape. On the other hand, the synthetic strategies are mostly essential in raising a compound's specific capacitance. Here, we report the synthesis of vanadium pentoxide nanoparticles using a cost effective solution combustion method. The synthesized material was characterized by X-ray diffraction analysis, UV-Vis Spectroscopy, FT-IR Spectroscopy, Scanning Electron Microscopy, Cyclic voltammetry, Galvanostatic Charge-discharge, and Electrochemical Impedance Spectroscopy. The crystallite size of obtained nanoparticles is 28 nm. The specific capacitance of Vanadium pentoxide nanoparticles is 310 F/g and is calculated at 1 A/g using Galvanostatic Charge-discharge method. The obtained specific capacitance is higher than the existing reports on V2O5 nanoparticles. |
first_indexed | 2024-10-01T03:45:31Z |
format | Journal Article |
id | ntu-10356/164590 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T03:45:31Z |
publishDate | 2023 |
record_format | dspace |
spelling | ntu-10356/1645902023-02-11T23:32:46Z A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications Sutrave, Shivani Konda, Shireesha Velpula, Divya Volety, Sriram Ankith Ravula, Sugunakar Reddy Chidurala, Shilpa Chakra Tumma, Bala Narsaiah Energy Research Institute @ NTU (ERI@N) Engineering::Electrical and electronic engineering Supercapacitors Electrolyte The enhanced power density, long term cycling stability, and fast rate of operation, makes supercapacitors as desirable energy storage devices. Though metal oxides play a significant part in energy storage systems, Vanadium oxides have piqued the interest of electrochemists due to their multi-valency, potential window, unique layer structure, affordability, and plentiful availability. Vanadium pentoxide typically has relatively low specific capacitance due to its weak electrical conductivity and ionic diffusivity. However, these properties can be enhanced by encasing vanadium pentoxide in metal or carbonaceous materials, reducing it to the nanoscale, or changing its shape. On the other hand, the synthetic strategies are mostly essential in raising a compound's specific capacitance. Here, we report the synthesis of vanadium pentoxide nanoparticles using a cost effective solution combustion method. The synthesized material was characterized by X-ray diffraction analysis, UV-Vis Spectroscopy, FT-IR Spectroscopy, Scanning Electron Microscopy, Cyclic voltammetry, Galvanostatic Charge-discharge, and Electrochemical Impedance Spectroscopy. The crystallite size of obtained nanoparticles is 28 nm. The specific capacitance of Vanadium pentoxide nanoparticles is 310 F/g and is calculated at 1 A/g using Galvanostatic Charge-discharge method. The obtained specific capacitance is higher than the existing reports on V2O5 nanoparticles. Published version The authors would like to thank the Department of Science and Technology in New Delhi for its generous financial support for the study under the DST Young Scientist and Technologist, SEED division SP/YO/2019/1599(G) and Science & Engineering Research Board (no. SERB/F/7867/2019-2020). 2023-02-06T02:51:29Z 2023-02-06T02:51:29Z 2022 Journal Article Sutrave, S., Konda, S., Velpula, D., Volety, S. A., Ravula, S. R., Chidurala, S. C. & Tumma, B. N. (2022). A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications. Applied Surface Science Advances, 12, 100331-. https://dx.doi.org/10.1016/j.apsadv.2022.100331 2666-5239 https://hdl.handle.net/10356/164590 10.1016/j.apsadv.2022.100331 2-s2.0-85141781853 12 100331 en Applied Surface Science Advances © 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). application/pdf |
spellingShingle | Engineering::Electrical and electronic engineering Supercapacitors Electrolyte Sutrave, Shivani Konda, Shireesha Velpula, Divya Volety, Sriram Ankith Ravula, Sugunakar Reddy Chidurala, Shilpa Chakra Tumma, Bala Narsaiah A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title | A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title_full | A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title_fullStr | A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title_full_unstemmed | A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title_short | A simple solution combustion method for the synthesis of V2O5 nanostructures for supercapacitor applications |
title_sort | simple solution combustion method for the synthesis of v2o5 nanostructures for supercapacitor applications |
topic | Engineering::Electrical and electronic engineering Supercapacitors Electrolyte |
url | https://hdl.handle.net/10356/164590 |
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