A pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene-diboravinyl cation: boron analogue of vinyl cation
A boron analogue of vinyl cation, pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene (NHC)-diboravinyl cation 2+ , was synthesized by displacement of bromide in diborene 1 with excess pyridine. Experimental and computational studies showed that the positive charge is mainly at the B-B s...
Main Authors: | Fan, Jun, Chia, Pei-Ting, Zhang, Zheng-Feng, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai |
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Other Authors: | School of Chemistry, Chemical Engineering and Biotechnology |
Format: | Journal Article |
Language: | English |
Published: |
2023
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/164639 |
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