| Summary: | Polymer-based nanostructured systems have received relevant attention for exhibiting
remarkable improvements of mechanical, thermal, optical and other physicochemical
properties as compared to its pure components. With the improvements, it has led to the development of its use in many applications in the biomedical field today.
In this project, the morphology and mechanical behaviour of nano-composites formed by chitosan and polyhedral oligomeric silsesquioxane (POSS) and carbon nanotubes (CNT) used in applications such as membrane separations were studied, with the objective to find any correlation in the behaviour of the mechanical and thermal properties of nanocomposites with the amount of filler that is added incorporated into the polymer matrix.
Different amount of POSS loadings for 2 different types, namely Octa-Ammonium (OA)
and Octa Nitro Phenyl Silsesquioxane (ONPS), and single-walled carbon nanotubes
(SWCNT) were added into chitosan and the fibres spun using the wet-spinning method.
Mechanical tensile tests were conducted to determine the strength of the fibres. Analysis of the morphology of the fibres was conducted using Scanning Electron Microscopy
(SEM) and thermal properties of the nano-composites were analysed using
Thermogravimetric Analysis (TGA). The results indicated an increase in mechanical
properties of the nanocomposites up to a certain percentage of filler added, but a decrease in thermal stability. The improvements were significant for both types of POSS but not significant for SWCNT.
|
|---|