Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites

Polymer-based nanostructured systems have received relevant attention for exhibiting remarkable improvements of mechanical, thermal, optical and other physicochemical properties as compared to its pure components. With the improvements, it has led to the development of its use in many applications...

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Main Author: Lim, Zhi Cheng.
Other Authors: Wang Kean
Format: Final Year Project (FYP)
Language:English
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10356/16485
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author Lim, Zhi Cheng.
author2 Wang Kean
author_facet Wang Kean
Lim, Zhi Cheng.
author_sort Lim, Zhi Cheng.
collection NTU
description Polymer-based nanostructured systems have received relevant attention for exhibiting remarkable improvements of mechanical, thermal, optical and other physicochemical properties as compared to its pure components. With the improvements, it has led to the development of its use in many applications in the biomedical field today. In this project, the morphology and mechanical behaviour of nano-composites formed by chitosan and polyhedral oligomeric silsesquioxane (POSS) and carbon nanotubes (CNT) used in applications such as membrane separations were studied, with the objective to find any correlation in the behaviour of the mechanical and thermal properties of nanocomposites with the amount of filler that is added incorporated into the polymer matrix. Different amount of POSS loadings for 2 different types, namely Octa-Ammonium (OA) and Octa Nitro Phenyl Silsesquioxane (ONPS), and single-walled carbon nanotubes (SWCNT) were added into chitosan and the fibres spun using the wet-spinning method. Mechanical tensile tests were conducted to determine the strength of the fibres. Analysis of the morphology of the fibres was conducted using Scanning Electron Microscopy (SEM) and thermal properties of the nano-composites were analysed using Thermogravimetric Analysis (TGA). The results indicated an increase in mechanical properties of the nanocomposites up to a certain percentage of filler added, but a decrease in thermal stability. The improvements were significant for both types of POSS but not significant for SWCNT.
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spelling ntu-10356/164852023-03-03T15:37:30Z Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites Lim, Zhi Cheng. Wang Kean School of Chemical and Biomedical Engineering DRNTU::Engineering::Chemical engineering::Polymers and polymer manufacture Polymer-based nanostructured systems have received relevant attention for exhibiting remarkable improvements of mechanical, thermal, optical and other physicochemical properties as compared to its pure components. With the improvements, it has led to the development of its use in many applications in the biomedical field today. In this project, the morphology and mechanical behaviour of nano-composites formed by chitosan and polyhedral oligomeric silsesquioxane (POSS) and carbon nanotubes (CNT) used in applications such as membrane separations were studied, with the objective to find any correlation in the behaviour of the mechanical and thermal properties of nanocomposites with the amount of filler that is added incorporated into the polymer matrix. Different amount of POSS loadings for 2 different types, namely Octa-Ammonium (OA) and Octa Nitro Phenyl Silsesquioxane (ONPS), and single-walled carbon nanotubes (SWCNT) were added into chitosan and the fibres spun using the wet-spinning method. Mechanical tensile tests were conducted to determine the strength of the fibres. Analysis of the morphology of the fibres was conducted using Scanning Electron Microscopy (SEM) and thermal properties of the nano-composites were analysed using Thermogravimetric Analysis (TGA). The results indicated an increase in mechanical properties of the nanocomposites up to a certain percentage of filler added, but a decrease in thermal stability. The improvements were significant for both types of POSS but not significant for SWCNT. Bachelor of Engineering (Chemical and Biomolecular Engineering) 2009-05-26T07:53:27Z 2009-05-26T07:53:27Z 2009 2009 Final Year Project (FYP) http://hdl.handle.net/10356/16485 en Nanyang Technological University 75 p. application/pdf
spellingShingle DRNTU::Engineering::Chemical engineering::Polymers and polymer manufacture
Lim, Zhi Cheng.
Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title_full Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title_fullStr Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title_full_unstemmed Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title_short Fabrication and characterization of POSS and CNT reinforced chitosan matrix nano-composites
title_sort fabrication and characterization of poss and cnt reinforced chitosan matrix nano composites
topic DRNTU::Engineering::Chemical engineering::Polymers and polymer manufacture
url http://hdl.handle.net/10356/16485
work_keys_str_mv AT limzhicheng fabricationandcharacterizationofpossandcntreinforcedchitosanmatrixnanocomposites