Atroposelective access to 1,3-oxazepine-containing bridged biaryls via carbene-catalyzed desymmetrization of imines

Atroposelective access to 1,3-oxazepine-containing bridged biaryls via carbene-catalyzed desymmetrization of imines

We disclose herein an atroposelective synthesis of novel bridged biaryls containing medium-sized rings via N-heterocyclic carbene organocatalysis. The reaction starts with addition of the carbene catalyst to the aminophenol-derived aldimine substrate. Subsequent oxidation and intramolecular desymmet...

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Bibliographic Details
Main Authors: Yang, Xing, Wei, Liwen, Wu, Yuelin, Zhou, Liejin, Zhang, Xinglong, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Atropisomerism
Bridged Biaryls
Online Access:https://hdl.handle.net/10356/166232

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