One step development of high entropy alloy for high performance supercapacitors electrodes

Supercapacitor plays a crucial role in energy storage application, relying on its superior electrochemical performance, which is mainly determined by the electrode material used. Research on alternatives for pure carbon as the electrodes in the electric double-layer capacitor (EDLC) are carried o...

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Main Author: Liao, Yiyu
Other Authors: Huang Yizhong
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2023
Subjects:
Online Access:https://hdl.handle.net/10356/166602
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author Liao, Yiyu
author2 Huang Yizhong
author_facet Huang Yizhong
Liao, Yiyu
author_sort Liao, Yiyu
collection NTU
description Supercapacitor plays a crucial role in energy storage application, relying on its superior electrochemical performance, which is mainly determined by the electrode material used. Research on alternatives for pure carbon as the electrodes in the electric double-layer capacitor (EDLC) are carried out continuously in recent years, one typical solution is the utilization of High-entropy alloys (HEAs). HEAs are a relatively new class of materials that consist of multiple metallic elements in roughly equal proportions, which exhibit unique properties mechanically, electrically, and chemically. This project aims to synthesize an asymmetric solid supercapacitor using high-entropy alloy nanoparticles (HEA-NPs) decorated carbon cloth and an active carbon paper. The HEA-NPs consisted of 5 metallic elements: Chromium, Cobalt, Nickle, Manganese, and Zinc (CrCoNiMgZn) were synthesized on the carbon cloth using a pulsed laser irradiation (PLI) method, resulting in a highly conductive and porous nanocomposite electrode. The electrochemical performance of the HEA/carbon electrode was characterized, showing expected specific capacitance, superior rate capability as well as promising cycling stability. Lastly, the limitations of the study were identified, and recommendations for further exploration were suggested. This project is to provide a reference for the synthesis of HEA-NPs using PLI, insights into alternatives for electrode materials of EDLC, as well as the potentiality of HEA-NPs in sustainable energy storage applications.
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spelling ntu-10356/1666022023-05-13T16:45:41Z One step development of high entropy alloy for high performance supercapacitors electrodes Liao, Yiyu Huang Yizhong School of Materials Science and Engineering YZHuang@ntu.edu.sg Engineering::Materials Supercapacitor plays a crucial role in energy storage application, relying on its superior electrochemical performance, which is mainly determined by the electrode material used. Research on alternatives for pure carbon as the electrodes in the electric double-layer capacitor (EDLC) are carried out continuously in recent years, one typical solution is the utilization of High-entropy alloys (HEAs). HEAs are a relatively new class of materials that consist of multiple metallic elements in roughly equal proportions, which exhibit unique properties mechanically, electrically, and chemically. This project aims to synthesize an asymmetric solid supercapacitor using high-entropy alloy nanoparticles (HEA-NPs) decorated carbon cloth and an active carbon paper. The HEA-NPs consisted of 5 metallic elements: Chromium, Cobalt, Nickle, Manganese, and Zinc (CrCoNiMgZn) were synthesized on the carbon cloth using a pulsed laser irradiation (PLI) method, resulting in a highly conductive and porous nanocomposite electrode. The electrochemical performance of the HEA/carbon electrode was characterized, showing expected specific capacitance, superior rate capability as well as promising cycling stability. Lastly, the limitations of the study were identified, and recommendations for further exploration were suggested. This project is to provide a reference for the synthesis of HEA-NPs using PLI, insights into alternatives for electrode materials of EDLC, as well as the potentiality of HEA-NPs in sustainable energy storage applications. Bachelor of Engineering (Materials Engineering) 2023-05-08T01:45:47Z 2023-05-08T01:45:47Z 2023 Final Year Project (FYP) Liao, Y. (2023). One step development of high entropy alloy for high performance supercapacitors electrodes. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/166602 https://hdl.handle.net/10356/166602 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials
Liao, Yiyu
One step development of high entropy alloy for high performance supercapacitors electrodes
title One step development of high entropy alloy for high performance supercapacitors electrodes
title_full One step development of high entropy alloy for high performance supercapacitors electrodes
title_fullStr One step development of high entropy alloy for high performance supercapacitors electrodes
title_full_unstemmed One step development of high entropy alloy for high performance supercapacitors electrodes
title_short One step development of high entropy alloy for high performance supercapacitors electrodes
title_sort one step development of high entropy alloy for high performance supercapacitors electrodes
topic Engineering::Materials
url https://hdl.handle.net/10356/166602
work_keys_str_mv AT liaoyiyu onestepdevelopmentofhighentropyalloyforhighperformancesupercapacitorselectrodes