Structural and conformable designs for aqueous multifunctional batteries

A combination of structural and conformable batteries offers a pathway towards an increased payload capacity and alleviation of ‘range anxiety’ for electric vehicles through effective integration of mechanical stability and energy storage materials. This work focus on a holistic combination of aqueo...

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Main Authors: Lim, Gwendolyn Jia Hao, Chua, Rodney, Koh, Justin J., Chan, Kwok Kiong, Tang, Ernest Jun Jie, Teh, Vanessa, Srinivasan, Madhavi
Other Authors: School of Materials Science and Engineering
Format: Journal Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/168907
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author Lim, Gwendolyn Jia Hao
Chua, Rodney
Koh, Justin J.
Chan, Kwok Kiong
Tang, Ernest Jun Jie
Teh, Vanessa
Srinivasan, Madhavi
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Lim, Gwendolyn Jia Hao
Chua, Rodney
Koh, Justin J.
Chan, Kwok Kiong
Tang, Ernest Jun Jie
Teh, Vanessa
Srinivasan, Madhavi
author_sort Lim, Gwendolyn Jia Hao
collection NTU
description A combination of structural and conformable batteries offers a pathway towards an increased payload capacity and alleviation of ‘range anxiety’ for electric vehicles through effective integration of mechanical stability and energy storage materials. This work focus on a holistic combination of aqueous structural and conformable batteries in vehicles through a multifunctional direct (structural) approach (MFDA) and multifunctional conformable approach (MFCA), applied to the exterior and interior structure of a car, respectively. A highly safe and well-designed aqueous electrolyte composed of Li–Zn hybrid ions was adopted and was well compatible with both the MFDA and MFCA LiMn2O4 cathode system fabricated. A Young's Modulus of 13.57 ± 0.9 GPa for the MFDA cathode was achieved, an order of magnitude higher than conventional slurry coated cathode materials. Additionally, a high rate (5 A/g) capability and superior cycle stability (∼80.3 mAh/g after 1000 cycles @ 2 A/g) of the MFCA batteries with great deformation resilience are also demonstrated. This concept combination was successfully applied in a prototype toy car, and can guide the design of a new generation of structural batteries towards well-distributed energy storage throughout the vehicle.
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spelling ntu-10356/1689072023-06-22T02:51:37Z Structural and conformable designs for aqueous multifunctional batteries Lim, Gwendolyn Jia Hao Chua, Rodney Koh, Justin J. Chan, Kwok Kiong Tang, Ernest Jun Jie Teh, Vanessa Srinivasan, Madhavi School of Materials Science and Engineering Energy Research Institute @ NTU (ERI@N) Engineering::Materials Form Factor Energy Storage A combination of structural and conformable batteries offers a pathway towards an increased payload capacity and alleviation of ‘range anxiety’ for electric vehicles through effective integration of mechanical stability and energy storage materials. This work focus on a holistic combination of aqueous structural and conformable batteries in vehicles through a multifunctional direct (structural) approach (MFDA) and multifunctional conformable approach (MFCA), applied to the exterior and interior structure of a car, respectively. A highly safe and well-designed aqueous electrolyte composed of Li–Zn hybrid ions was adopted and was well compatible with both the MFDA and MFCA LiMn2O4 cathode system fabricated. A Young's Modulus of 13.57 ± 0.9 GPa for the MFDA cathode was achieved, an order of magnitude higher than conventional slurry coated cathode materials. Additionally, a high rate (5 A/g) capability and superior cycle stability (∼80.3 mAh/g after 1000 cycles @ 2 A/g) of the MFCA batteries with great deformation resilience are also demonstrated. This concept combination was successfully applied in a prototype toy car, and can guide the design of a new generation of structural batteries towards well-distributed energy storage throughout the vehicle. Agency for Science, Technology and Research (A*STAR) National Research Foundation (NRF) The authors acknowledge the grant from A*STAR under the Advanced Manufacturing and Engineering programmatic fund number A20H3g2140 and the National Research Foundation of Singapore (NRF) Investigatorship Award NRFI2017-08/ NRF2016NRF-NRFI001-22. 2023-06-22T02:51:37Z 2023-06-22T02:51:37Z 2023 Journal Article Lim, G. J. H., Chua, R., Koh, J. J., Chan, K. K., Tang, E. J. J., Teh, V. & Srinivasan, M. (2023). Structural and conformable designs for aqueous multifunctional batteries. Materials Today Energy, 33, 101255-. https://dx.doi.org/10.1016/j.mtener.2023.101255 2468-6069 https://hdl.handle.net/10356/168907 10.1016/j.mtener.2023.101255 2-s2.0-85148684388 33 101255 en A20H3g2140 NRFI2017-08/NRF2016NRF-NRFI001-22. Materials Today Energy © 2023 Elsevier Ltd. All rights reserved.
spellingShingle Engineering::Materials
Form Factor
Energy Storage
Lim, Gwendolyn Jia Hao
Chua, Rodney
Koh, Justin J.
Chan, Kwok Kiong
Tang, Ernest Jun Jie
Teh, Vanessa
Srinivasan, Madhavi
Structural and conformable designs for aqueous multifunctional batteries
title Structural and conformable designs for aqueous multifunctional batteries
title_full Structural and conformable designs for aqueous multifunctional batteries
title_fullStr Structural and conformable designs for aqueous multifunctional batteries
title_full_unstemmed Structural and conformable designs for aqueous multifunctional batteries
title_short Structural and conformable designs for aqueous multifunctional batteries
title_sort structural and conformable designs for aqueous multifunctional batteries
topic Engineering::Materials
Form Factor
Energy Storage
url https://hdl.handle.net/10356/168907
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