N-phosphinoamidinato silylene- and phosphine-borylborylene complexes
This work describes a straightforward method to synthesize a borylborylene without proceeding via the rearrangement of a diborene. An amidinato amidosilylene [LSiNMe2] (L = PhC(NtBu)2) and PMe3 were reacted with an N-phosphinoamidinato diborane 1 and KC8 to form a stable silylene-borylborylene 2 and...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2023
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| Online Access: | https://hdl.handle.net/10356/168936 |
| _version_ | 1824454803197001728 |
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| author | Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| author2 | School of Chemistry, Chemical Engineering and Biotechnology |
| author_facet | School of Chemistry, Chemical Engineering and Biotechnology Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| author_sort | Fan, Jun |
| collection | NTU |
| description | This work describes a straightforward method to synthesize a borylborylene without proceeding via the rearrangement of a diborene. An amidinato amidosilylene [LSiNMe2] (L = PhC(NtBu)2) and PMe3 were reacted with an N-phosphinoamidinato diborane 1 and KC8 to form a stable silylene-borylborylene 2 and a persistent phosphine-borylborylene 3, respectively. Compound 2 is stable as the borylene center is well stabilized by the silylene donor and boryl substituent, whereas compound 3 is unstable in solution due to labile PMe3. The latter was illustrated by reacting compound 3 with Ar'NC (Ar' = 2,6-Me2C6H3), where Ar'NC displaced PMe3 and inserted into the N-phosphinoamidinate ligand and B-B bond to form compound 4. |
| first_indexed | 2025-02-19T03:28:07Z |
| format | Journal Article |
| id | ntu-10356/168936 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:28:07Z |
| publishDate | 2023 |
| record_format | dspace |
| spelling | ntu-10356/1689362024-06-14T15:31:48Z N-phosphinoamidinato silylene- and phosphine-borylborylene complexes Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai School of Chemistry, Chemical Engineering and Biotechnology Chemistry Boron compounds A-Stable This work describes a straightforward method to synthesize a borylborylene without proceeding via the rearrangement of a diborene. An amidinato amidosilylene [LSiNMe2] (L = PhC(NtBu)2) and PMe3 were reacted with an N-phosphinoamidinato diborane 1 and KC8 to form a stable silylene-borylborylene 2 and a persistent phosphine-borylborylene 3, respectively. Compound 2 is stable as the borylene center is well stabilized by the silylene donor and boryl substituent, whereas compound 3 is unstable in solution due to labile PMe3. The latter was illustrated by reacting compound 3 with Ar'NC (Ar' = 2,6-Me2C6H3), where Ar'NC displaced PMe3 and inserted into the N-phosphinoamidinate ligand and B-B bond to form compound 4. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Submitted/Accepted version C.-W.S. thanks the Ministry of Education Singapore, AcRF Tier 2 (MOE2019-T2-2-129) and A*STAR MTC Individual Research Grant (M21K2c0117). 2023-06-23T02:14:04Z 2023-06-23T02:14:04Z 2023 Journal Article Fan, J., Yang, M., Su, M. & So, C. (2023). N-phosphinoamidinato silylene- and phosphine-borylborylene complexes. Inorganic Chemistry, 62(2), 863-870. https://dx.doi.org/10.1021/acs.inorgchem.2c03660 0020-1669 https://hdl.handle.net/10356/168936 10.1021/acs.inorgchem.2c03660 36600552 2-s2.0-85146022470 2 62 863 870 en MOE2019-T2-2-129 M21K2c0117 Inorganic Chemistry © 2023 American Chemical Society. All rights reserved.This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1021/acs.inorgchem.2c03660. application/pdf |
| spellingShingle | Chemistry Boron compounds A-Stable Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title | N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title_full | N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title_fullStr | N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title_full_unstemmed | N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title_short | N-phosphinoamidinato silylene- and phosphine-borylborylene complexes |
| title_sort | n phosphinoamidinato silylene and phosphine borylborylene complexes |
| topic | Chemistry Boron compounds A-Stable |
| url | https://hdl.handle.net/10356/168936 |
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