A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers

Proton exchange membrane water electrolyzer (PEMWE) is a major enabler of green hydrogen production. The development of water electrolyzers is a vital step in driving the progress of a hydrogen-based economy. The system inside the electrolyzer is a zero-gap cell featuring low ohmic resistance and bo...

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Main Authors: Lin, Xinlong, Seow, Justin Zhu Yeow, Xu, Jason Zhichuan
Other Authors: School of Materials Science and Engineering
Format: Journal Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/170012
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author Lin, Xinlong
Seow, Justin Zhu Yeow
Xu, Jason Zhichuan
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Lin, Xinlong
Seow, Justin Zhu Yeow
Xu, Jason Zhichuan
author_sort Lin, Xinlong
collection NTU
description Proton exchange membrane water electrolyzer (PEMWE) is a major enabler of green hydrogen production. The development of water electrolyzers is a vital step in driving the progress of a hydrogen-based economy. The system inside the electrolyzer is a zero-gap cell featuring low ohmic resistance and boosted mass transport, leading to higher energy efficiency and minimized capital cost. Besides, utilizing PEM in the electrolyzer for sustainable hydrogen production enables the system to perform with many advantages, including superior energy efficiency, higher hydrogen purity, and high flexibility. Therefore, as PEM electrolyzers continue to evolve, sustainable hydrogen production on a larger scale will be realized in the near future. This review summarizes the status quo of PEM water electrolyzers in the past four years. We will start with a brief introduction of the core of a water electrolyzer, namely the membrane electrode assembly (MEA), which will be followed by an introduction of fabrication methods of MEA, including CCM methods, catalyst-coated electrode methods, and other innovative fabrication methods. Next, we will summarize recent attempts to modify electrodes and membranes in MEAs to promote the performance of PEMWE. Subsequently, catalyst development for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in MEA is discussed, highlighting novel HER/OER catalysts and strategies to reduce the content of noble metals. Lastly, conclusion and perspectives are provided to present a blueprint to inspire the future development of PEMWE.
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spelling ntu-10356/1700122023-08-25T15:44:05Z A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers Lin, Xinlong Seow, Justin Zhu Yeow Xu, Jason Zhichuan School of Materials Science and Engineering Center for Advanced Catalysis Science and Technology Energy Research Institute @ NTU (ERI@N) Engineering::Materials Water Electrolysis Membrane Electrode Assembly Proton exchange membrane water electrolyzer (PEMWE) is a major enabler of green hydrogen production. The development of water electrolyzers is a vital step in driving the progress of a hydrogen-based economy. The system inside the electrolyzer is a zero-gap cell featuring low ohmic resistance and boosted mass transport, leading to higher energy efficiency and minimized capital cost. Besides, utilizing PEM in the electrolyzer for sustainable hydrogen production enables the system to perform with many advantages, including superior energy efficiency, higher hydrogen purity, and high flexibility. Therefore, as PEM electrolyzers continue to evolve, sustainable hydrogen production on a larger scale will be realized in the near future. This review summarizes the status quo of PEM water electrolyzers in the past four years. We will start with a brief introduction of the core of a water electrolyzer, namely the membrane electrode assembly (MEA), which will be followed by an introduction of fabrication methods of MEA, including CCM methods, catalyst-coated electrode methods, and other innovative fabrication methods. Next, we will summarize recent attempts to modify electrodes and membranes in MEAs to promote the performance of PEMWE. Subsequently, catalyst development for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in MEA is discussed, highlighting novel HER/OER catalysts and strategies to reduce the content of noble metals. Lastly, conclusion and perspectives are provided to present a blueprint to inspire the future development of PEMWE. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Published version This work is supported by the Singapore Ministry of Education (MOE) Tier 1 Grant (RG62/21), MOE Tier 2 Grant (MOE-T2EP10220-0001) and A*STAR (Agency for Science, Technology and Research) under its LCERFI program (Award No. U2102d2002). 2023-08-21T06:56:22Z 2023-08-21T06:56:22Z 2023 Journal Article Lin, X., Seow, J. Z. Y. & Xu, J. Z. (2023). A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers. JPhys Energy, 5(3), 034003-. https://dx.doi.org/10.1088/2515-7655/acccb1 2515-7655 https://hdl.handle.net/10356/170012 10.1088/2515-7655/acccb1 2-s2.0-85158875970 3 5 034003 en RG62/21 MOE-T2EP10220-0001 U2102d2002 JPhys Energy © 2023 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. application/pdf
spellingShingle Engineering::Materials
Water Electrolysis
Membrane Electrode Assembly
Lin, Xinlong
Seow, Justin Zhu Yeow
Xu, Jason Zhichuan
A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title_full A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title_fullStr A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title_full_unstemmed A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title_short A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
title_sort brief introduction of electrode fabrication for proton exchange membrane water electrolyzers
topic Engineering::Materials
Water Electrolysis
Membrane Electrode Assembly
url https://hdl.handle.net/10356/170012
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