N-phosphinoamidinato silicon(I) and silicon(II) compounds
This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to...
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| Format: | Thesis-Master by Research |
| Language: | English |
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Nanyang Technological University
2023
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| Online Access: | https://hdl.handle.net/10356/170104 |
| _version_ | 1811682012081160192 |
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| author | Phang, Isabel Si Jia |
| author2 | So Cheuk Wai |
| author_facet | So Cheuk Wai Phang, Isabel Si Jia |
| author_sort | Phang, Isabel Si Jia |
| collection | NTU |
| description | This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. |
| first_indexed | 2024-10-01T03:50:04Z |
| format | Thesis-Master by Research |
| id | ntu-10356/170104 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:50:04Z |
| publishDate | 2023 |
| publisher | Nanyang Technological University |
| record_format | dspace |
| spelling | ntu-10356/1701042023-09-04T07:32:08Z N-phosphinoamidinato silicon(I) and silicon(II) compounds Phang, Isabel Si Jia So Cheuk Wai School of Chemistry, Chemical Engineering and Biotechnology CWSo@ntu.edu.sg Science::Chemistry This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. Master of Science 2023-08-28T06:10:51Z 2023-08-28T06:10:51Z 2023 Thesis-Master by Research Phang, I. S. J. (2023). N-phosphinoamidinato silicon(I) and silicon(II) compounds. Master's thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/170104 https://hdl.handle.net/10356/170104 10.32657/10356/170104 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
| spellingShingle | Science::Chemistry Phang, Isabel Si Jia N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title | N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_full | N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_fullStr | N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_full_unstemmed | N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_short | N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_sort | n phosphinoamidinato silicon i and silicon ii compounds |
| topic | Science::Chemistry |
| url | https://hdl.handle.net/10356/170104 |
| work_keys_str_mv | AT phangisabelsijia nphosphinoamidinatosiliconiandsiliconiicompounds |