Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery
Applications of environmentally friendly and low-cost biomaterials for membrane preparation offer unparalleled advantages over traditional synthetic polymer membrane. Herein, a novel collagen/casein/chitosan composite material was designed to synthesize TFC membrane for acid recovery from acidic was...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2023
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/170106 |
| _version_ | 1824454655319474176 |
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| author | Xiao, Pei Li, Xin Li, Lei Liu, Fei Wang, Yi (Alex) Li, Jian |
| author2 | Nanyang Environment and Water Research Institute |
| author_facet | Nanyang Environment and Water Research Institute Xiao, Pei Li, Xin Li, Lei Liu, Fei Wang, Yi (Alex) Li, Jian |
| author_sort | Xiao, Pei |
| collection | NTU |
| description | Applications of environmentally friendly and low-cost biomaterials for membrane preparation offer unparalleled advantages over traditional synthetic polymer membrane. Herein, a novel collagen/casein/chitosan composite material was designed to synthesize TFC membrane for acid recovery from acidic waste stream. A vacuum filtration method was used to precious adjust the thickness of the functional layer while glutaraldehyde was adopted as crosslinking agent to preserve surface charge property of anion-exchange membranes (AEM) at acidic conditions. The electrostatic interactions and hydrogen bonding of these biopolymers endowed the TFC membrane with enhanced stability. At optimized conditions with 0.15 mL collagen/casein/chitosan composites decoration, the TFC membrane with a functional layer thickness of around 628.4 nm exhibited an excellent acid permeance (UH+ = 0.034 m h−1) and a high H+/ Fe2+ separation factor up to 33.8. This facile strategy provides a useful guideline for constructing highly efficient TFC membrane for acid recovery and broadens the application of biomaterials for membrane application at harsh environments. |
| first_indexed | 2025-02-19T03:25:46Z |
| format | Journal Article |
| id | ntu-10356/170106 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:25:46Z |
| publishDate | 2023 |
| record_format | dspace |
| spelling | ntu-10356/1701062023-08-29T06:44:21Z Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery Xiao, Pei Li, Xin Li, Lei Liu, Fei Wang, Yi (Alex) Li, Jian Nanyang Environment and Water Research Institute Singapore Membrane Technology Centre Engineering::Environmental engineering Acid Recovery Diffusion Dialysis Applications of environmentally friendly and low-cost biomaterials for membrane preparation offer unparalleled advantages over traditional synthetic polymer membrane. Herein, a novel collagen/casein/chitosan composite material was designed to synthesize TFC membrane for acid recovery from acidic waste stream. A vacuum filtration method was used to precious adjust the thickness of the functional layer while glutaraldehyde was adopted as crosslinking agent to preserve surface charge property of anion-exchange membranes (AEM) at acidic conditions. The electrostatic interactions and hydrogen bonding of these biopolymers endowed the TFC membrane with enhanced stability. At optimized conditions with 0.15 mL collagen/casein/chitosan composites decoration, the TFC membrane with a functional layer thickness of around 628.4 nm exhibited an excellent acid permeance (UH+ = 0.034 m h−1) and a high H+/ Fe2+ separation factor up to 33.8. This facile strategy provides a useful guideline for constructing highly efficient TFC membrane for acid recovery and broadens the application of biomaterials for membrane application at harsh environments. This work was supported by the National Natural Science Foundation of China (Grant Nos: 21908076). 2023-08-28T06:01:27Z 2023-08-28T06:01:27Z 2023 Journal Article Xiao, P., Li, X., Li, L., Liu, F., Wang, Y. (. & Li, J. (2023). Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery. Desalination, 558, 116627-. https://dx.doi.org/10.1016/j.desal.2023.116627 0011-9164 https://hdl.handle.net/10356/170106 10.1016/j.desal.2023.116627 2-s2.0-85153373943 558 116627 en Desalination © 2023 Published by Elsevier B. V. All rights reserved. |
| spellingShingle | Engineering::Environmental engineering Acid Recovery Diffusion Dialysis Xiao, Pei Li, Xin Li, Lei Liu, Fei Wang, Yi (Alex) Li, Jian Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title | Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title_full | Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title_fullStr | Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title_full_unstemmed | Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title_short | Bio-functional collagen/casein/chitosan scaffolds regulated porous TFC membrane for acid recovery |
| title_sort | bio functional collagen casein chitosan scaffolds regulated porous tfc membrane for acid recovery |
| topic | Engineering::Environmental engineering Acid Recovery Diffusion Dialysis |
| url | https://hdl.handle.net/10356/170106 |
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