Kinetic and dynamic kinetic resolution of racemic tertiary bromides by pentanidium‐catalyzed phase‐transfer azidation

Kinetic and dynamic kinetic resolution of racemic tertiary bromides by pentanidium‐catalyzed phase‐transfer azidation

We have developed a method to afford enantiomerically enriched tertiary azides and bromides through pentanidium-catalyzed kinetic resolution (KR) of racemic tertiary bromides under base-free conditions. We found that the absence of water is crucial to attain a high selectivity factor (s). On the oth...

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Bibliographic Details
Main Authors: Ren, Jingyun, Ban, Xu, Zhang, Xin, Tan, Siu Min, Lee, Richmond, Tan, Choon-Hong
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Journal Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Asymmetric Catalysis
Dynamic Kinetic Resolution
Online Access:https://hdl.handle.net/10356/170451

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