Vanadium oxide: phase diagrams, structures, synthesis, and applications
Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and...
| Main Authors: | , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2023
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/170633 |
| _version_ | 1811694527201673216 |
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| author | Hu, Peng Hu, Ping Vu, Tuan Duc Li, Ming Wang, Shancheng Ke, Yujie Zeng, Xianting Mai, Liqiang Long, Yi |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Hu, Peng Hu, Ping Vu, Tuan Duc Li, Ming Wang, Shancheng Ke, Yujie Zeng, Xianting Mai, Liqiang Long, Yi |
| author_sort | Hu, Peng |
| collection | NTU |
| description | Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V2O3, V3O5, VO2, V3O7, V2O5, V2O2, V6O13, and V4O9. We begin with a tutorial on the phase diagram of the V-O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications. |
| first_indexed | 2024-10-01T07:08:59Z |
| format | Journal Article |
| id | ntu-10356/170633 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:08:59Z |
| publishDate | 2023 |
| record_format | dspace |
| spelling | ntu-10356/1706332023-09-29T15:44:54Z Vanadium oxide: phase diagrams, structures, synthesis, and applications Hu, Peng Hu, Ping Vu, Tuan Duc Li, Ming Wang, Shancheng Ke, Yujie Zeng, Xianting Mai, Liqiang Long, Yi School of Materials Science and Engineering Institute of Materials Research and Engineering (IMRE), A*STAR Engineering::Materials Vanadium Dioxide Phase Diagrams Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V2O3, V3O5, VO2, V3O7, V2O5, V2O2, V6O13, and V4O9. We begin with a tutorial on the phase diagram of the V-O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications. Ministry of Education (MOE) Published version Peng Hu acknowledges the financial support from the National Natural Science Foundation of China (No. 51803168), the Key Research and Development Program of Shaanxi Province (2022GY-356), and the Youth Innovation Team of Shaanxi Universities. L.M. acknowledges the financial support from the National Key Research and Development Program of China (Grant No. 2020YFA0715000), the National Natural Science Foundation of China (Grant No. 52127816), and the Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (XHT2020-003). Ping Hu acknowledges the financial support from the Guangdong Basic and Applied Basic Research Foundation (2021A1515110059). Y.L. would like to acknowledge the funding support from MOE-T2EP50221-0014, Ministry of Education, Singapore and Global STEM Professorship Scheme sponsored by the Government of the Hong Kong Special Administrative Region. 2023-09-25T01:59:24Z 2023-09-25T01:59:24Z 2023 Journal Article Hu, P., Hu, P., Vu, T. D., Li, M., Wang, S., Ke, Y., Zeng, X., Mai, L. & Long, Y. (2023). Vanadium oxide: phase diagrams, structures, synthesis, and applications. Chemical Reviews, 123(8), 4353-4415. https://dx.doi.org/10.1021/acs.chemrev.2c00546 0009-2665 https://hdl.handle.net/10356/170633 10.1021/acs.chemrev.2c00546 36972332 2-s2.0-85151387180 8 123 4353 4415 en MOE-T2EP50221-0014 Chemical Reviews © 2023 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0. application/pdf |
| spellingShingle | Engineering::Materials Vanadium Dioxide Phase Diagrams Hu, Peng Hu, Ping Vu, Tuan Duc Li, Ming Wang, Shancheng Ke, Yujie Zeng, Xianting Mai, Liqiang Long, Yi Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title | Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title_full | Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title_fullStr | Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title_full_unstemmed | Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title_short | Vanadium oxide: phase diagrams, structures, synthesis, and applications |
| title_sort | vanadium oxide phase diagrams structures synthesis and applications |
| topic | Engineering::Materials Vanadium Dioxide Phase Diagrams |
| url | https://hdl.handle.net/10356/170633 |
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