Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes
The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2 ) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au-Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic ca...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2023
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/171088 |
| _version_ | 1826112785060200448 |
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| author | Feng, Zhongtao Wang, Liliang Sharifah Nadhirah Binte Shaik Mohammed Rao, Bin Kinjo, Rei |
| author2 | School of Chemistry, Chemical Engineering and Biotechnology |
| author_facet | School of Chemistry, Chemical Engineering and Biotechnology Feng, Zhongtao Wang, Liliang Sharifah Nadhirah Binte Shaik Mohammed Rao, Bin Kinjo, Rei |
| author_sort | Feng, Zhongtao |
| collection | NTU |
| description | The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2 ) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au-Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7. |
| first_indexed | 2024-10-01T03:12:48Z |
| format | Journal Article |
| id | ntu-10356/171088 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:12:48Z |
| publishDate | 2023 |
| record_format | dspace |
| spelling | ntu-10356/1710882023-10-13T15:31:42Z Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes Feng, Zhongtao Wang, Liliang Sharifah Nadhirah Binte Shaik Mohammed Rao, Bin Kinjo, Rei School of Chemistry, Chemical Engineering and Biotechnology Science::Chemistry Germylene Copper The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2 ) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au-Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7. Ministry of Education (MOE) Submitted/Accepted version We are grateful to Nanyang Technological University (NTU) and the Singapore Ministry of Education (MOE−T2EP10220-0002) for financial support. 2023-10-12T12:49:12Z 2023-10-12T12:49:12Z 2023 Journal Article Feng, Z., Wang, L., Sharifah Nadhirah Binte Shaik Mohammed, Rao, B. & Kinjo, R. (2023). Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes. Chemistry - An Asian Journal, 18(19), e202300634-. https://dx.doi.org/10.1002/asia.202300634 1861-4728 https://hdl.handle.net/10356/171088 10.1002/asia.202300634 37641951 2-s2.0-85170089527 19 18 e202300634 en MOE−T2EP10220-0002 Chemistry - An Asian Journal © 2023 Wiley-VCHGmbH. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1002/asia.202300634. application/pdf |
| spellingShingle | Science::Chemistry Germylene Copper Feng, Zhongtao Wang, Liliang Sharifah Nadhirah Binte Shaik Mohammed Rao, Bin Kinjo, Rei Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title_full | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title_fullStr | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title_full_unstemmed | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title_short | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes |
| title_sort | reactivity of cyclic alkyl amino germylene towards copper i and gold i complexes |
| topic | Science::Chemistry Germylene Copper |
| url | https://hdl.handle.net/10356/171088 |
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