A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-cata...
| Main Authors: | , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2023
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/171403 |
| _version_ | 1811680462241792000 |
|---|---|
| author | Zhang, Ting Lv, Yongheng Zhang, Zhenguo Jia, Zhenhua Loh, Teck-Peng |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Zhang, Ting Lv, Yongheng Zhang, Zhenguo Jia, Zhenhua Loh, Teck-Peng |
| author_sort | Zhang, Ting |
| collection | NTU |
| description | Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope. |
| first_indexed | 2024-10-01T03:25:26Z |
| format | Journal Article |
| id | ntu-10356/171403 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:25:26Z |
| publishDate | 2023 |
| record_format | dspace |
| spelling | ntu-10356/1714032023-11-06T15:34:55Z A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles Zhang, Ting Lv, Yongheng Zhang, Zhenguo Jia, Zhenhua Loh, Teck-Peng School of Physical and Mathematical Sciences Science::Chemistry Lanthanide Praseodymium Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University Submitted/Accepted version We thank the financial support from the Start-up Grant of Nanjing Tech University (Nos. 38274017103, 38037037). T.-P.L. thanks the financial support from Distinguished University Professor grant (Nanyang Technological University), AcRF Tier 1 grants from the Ministry of Education of Singapore (RG 107/19, RG 11/20 and RT 14/20), and the Agency for Science, Technology and Research (A*STAR) under its MTC Individual Research Grants (M21K2c0114). 2023-10-24T03:23:25Z 2023-10-24T03:23:25Z 2023 Journal Article Zhang, T., Lv, Y., Zhang, Z., Jia, Z. & Loh, T. (2023). A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles. Organic Letters, 25(24), 4468-4472. https://dx.doi.org/10.1021/acs.orglett.3c01449 1523-7060 https://hdl.handle.net/10356/171403 10.1021/acs.orglett.3c01449 37294030 2-s2.0-85163559125 24 25 4468 4472 en RG 107/19 RG 11/20 RT 14/20 M21K2c0114 Organic Letters © 2023 American Chemical Society. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1021/acs.orglett.3c01449. application/pdf |
| spellingShingle | Science::Chemistry Lanthanide Praseodymium Zhang, Ting Lv, Yongheng Zhang, Zhenguo Jia, Zhenhua Loh, Teck-Peng A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title | A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title_full | A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title_fullStr | A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title_full_unstemmed | A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title_short | A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles |
| title_sort | rare earth metal catalyzed aerobic dehydrogenation of n heterocycles |
| topic | Science::Chemistry Lanthanide Praseodymium |
| url | https://hdl.handle.net/10356/171403 |
| work_keys_str_mv | AT zhangting arareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT lvyongheng arareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT zhangzhenguo arareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT jiazhenhua arareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT lohteckpeng arareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT zhangting rareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT lvyongheng rareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT zhangzhenguo rareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT jiazhenhua rareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles AT lohteckpeng rareearthmetalcatalyzedaerobicdehydrogenationofnheterocycles |