Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis

Traditional fossil fuels come with environmental challenges like air pollution and global warming. As these resources dwindle due to finite reserves, the urgent need for sustainable, clean, and affordable energy options becomes evident. Decarbonization efforts have notably sped up the advancement of...

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Main Author: Wang, Yong
Other Authors: Liu Zheng
Format: Thesis-Doctor of Philosophy
Language:English
Published: Nanyang Technological University 2023
Subjects:
Online Access:https://hdl.handle.net/10356/171528
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author Wang, Yong
author2 Liu Zheng
author_facet Liu Zheng
Wang, Yong
author_sort Wang, Yong
collection NTU
description Traditional fossil fuels come with environmental challenges like air pollution and global warming. As these resources dwindle due to finite reserves, the urgent need for sustainable, clean, and affordable energy options becomes evident. Decarbonization efforts have notably sped up the advancement of renewable energy technologies. While solar and wind power have become more cost-competitive thanks to technological strides, their intermittent nature requires solutions for storing energy. Water electrolysis stands out as a technology capable of storing surplus electricity from renewables by splitting water into hydrogen and oxygen. This hydrogen, when used in fuel cells, generates electricity with only water vapor as a byproduct, showing promise as a green energy source. Presently, just 4% of hydrogen comes from renewable-powered electrolysis; most is from steam-methane reforming, a process emitting significant carbon dioxide. The high cost of precious metals used as electrocatalysts in electrolysis and fuel cells is the primary barrier to their widespread adoption. Seeking affordable, efficient, and durable catalyst alternatives is crucial to making these green technologies cost-effective. This thesis focuses on creating low-cost, efficient alloy-based electrocatalysts to enhance the cost-effectiveness and efficiency of these technologies. By exploring various alloys and their performance in energy systems, the research uncovers the composition-structure-property relationship, offering insights for optimizing electrocatalyst design and synthesis.
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spelling ntu-10356/1715282024-01-07T10:03:53Z Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis Wang, Yong Liu Zheng School of Materials Science and Engineering Huang Yizhong z.liu@ntu.edu.sg, yzhuang@ntu.edu.sg Engineering::Materials Traditional fossil fuels come with environmental challenges like air pollution and global warming. As these resources dwindle due to finite reserves, the urgent need for sustainable, clean, and affordable energy options becomes evident. Decarbonization efforts have notably sped up the advancement of renewable energy technologies. While solar and wind power have become more cost-competitive thanks to technological strides, their intermittent nature requires solutions for storing energy. Water electrolysis stands out as a technology capable of storing surplus electricity from renewables by splitting water into hydrogen and oxygen. This hydrogen, when used in fuel cells, generates electricity with only water vapor as a byproduct, showing promise as a green energy source. Presently, just 4% of hydrogen comes from renewable-powered electrolysis; most is from steam-methane reforming, a process emitting significant carbon dioxide. The high cost of precious metals used as electrocatalysts in electrolysis and fuel cells is the primary barrier to their widespread adoption. Seeking affordable, efficient, and durable catalyst alternatives is crucial to making these green technologies cost-effective. This thesis focuses on creating low-cost, efficient alloy-based electrocatalysts to enhance the cost-effectiveness and efficiency of these technologies. By exploring various alloys and their performance in energy systems, the research uncovers the composition-structure-property relationship, offering insights for optimizing electrocatalyst design and synthesis. Doctor of Philosophy 2023-10-30T02:15:05Z 2023-10-30T02:15:05Z 2023 Thesis-Doctor of Philosophy Wang, Y. (2023). Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/171528 https://hdl.handle.net/10356/171528 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). Nanyang Technological University
spellingShingle Engineering::Materials
Wang, Yong
Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title_full Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title_fullStr Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title_full_unstemmed Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title_short Composition and structure engineering of FeNi-based alloys for efficient electrocatalysis
title_sort composition and structure engineering of feni based alloys for efficient electrocatalysis
topic Engineering::Materials
url https://hdl.handle.net/10356/171528
work_keys_str_mv AT wangyong compositionandstructureengineeringoffenibasedalloysforefficientelectrocatalysis