Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells

The La9.5Si6O26.25 apatite type electrolyte was tested out with pure LSCF and LSM cathodes. It was benchmarked with other commonly used electrolytes such as GDC for intermediate temperature solid oxide fuel cells (IT-SOFCs) and YSZ for high temperature SOFCs (HT-SOFCs). XRD results of YSZ, LSM and N...

Full description

Bibliographic Details
Main Author: Heah, Min An.
Other Authors: Jiang San Ping
Format: Final Year Project (FYP)
Language:English
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10356/17170
_version_ 1824454950771490816
author Heah, Min An.
author2 Jiang San Ping
author_facet Jiang San Ping
Heah, Min An.
author_sort Heah, Min An.
collection NTU
description The La9.5Si6O26.25 apatite type electrolyte was tested out with pure LSCF and LSM cathodes. It was benchmarked with other commonly used electrolytes such as GDC for intermediate temperature solid oxide fuel cells (IT-SOFCs) and YSZ for high temperature SOFCs (HT-SOFCs). XRD results of YSZ, LSM and NiO calcined with La9.5Si6O26.25 showed no presence of new phases at all selected temperatures. On the other hand, XRD results of GDC, LSCF and SSC calcined with La9.5Si6O26.25 have peak variations in their diffractograms as temperature was raised. EIS tests under the temperature range of 700°C to 900°C and oxygen partial pressures of 0.01 – 1 atm were done for both LSM and LSCF cathodes. At 0.21 atm and 900°C, LSCF and LSM cathode impedance values were 0.272 Ωcm2 and 5.169 Ωcm2 respectively when used with the apatite electrolyte. These results were higher than the benchmarks.
first_indexed 2025-02-19T03:30:27Z
format Final Year Project (FYP)
id ntu-10356/17170
institution Nanyang Technological University
language English
last_indexed 2025-02-19T03:30:27Z
publishDate 2009
record_format dspace
spelling ntu-10356/171702023-03-04T18:52:59Z Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells Heah, Min An. Jiang San Ping School of Mechanical and Aerospace Engineering DRNTU::Engineering::Mechanical engineering::Alternative, renewable energy sources The La9.5Si6O26.25 apatite type electrolyte was tested out with pure LSCF and LSM cathodes. It was benchmarked with other commonly used electrolytes such as GDC for intermediate temperature solid oxide fuel cells (IT-SOFCs) and YSZ for high temperature SOFCs (HT-SOFCs). XRD results of YSZ, LSM and NiO calcined with La9.5Si6O26.25 showed no presence of new phases at all selected temperatures. On the other hand, XRD results of GDC, LSCF and SSC calcined with La9.5Si6O26.25 have peak variations in their diffractograms as temperature was raised. EIS tests under the temperature range of 700°C to 900°C and oxygen partial pressures of 0.01 – 1 atm were done for both LSM and LSCF cathodes. At 0.21 atm and 900°C, LSCF and LSM cathode impedance values were 0.272 Ωcm2 and 5.169 Ωcm2 respectively when used with the apatite electrolyte. These results were higher than the benchmarks. Bachelor of Engineering (Mechanical Engineering) 2009-06-01T04:05:01Z 2009-06-01T04:05:01Z 2009 2009 Final Year Project (FYP) http://hdl.handle.net/10356/17170 en Nanyang Technological University 66 p. application/pdf
spellingShingle DRNTU::Engineering::Mechanical engineering::Alternative, renewable energy sources
Heah, Min An.
Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title_full Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title_fullStr Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title_full_unstemmed Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title_short Preparation and characterization of apatite/cathode interfaces of solid oxide fuel cells
title_sort preparation and characterization of apatite cathode interfaces of solid oxide fuel cells
topic DRNTU::Engineering::Mechanical engineering::Alternative, renewable energy sources
url http://hdl.handle.net/10356/17170
work_keys_str_mv AT heahminan preparationandcharacterizationofapatitecathodeinterfacesofsolidoxidefuelcells