Helical fused 1,2:8,9-dibenzozethrene oligomers with up to 201° end-to-end twist: "one-pot" synthesis and chiral resolution

Helical fused 1,2:8,9-dibenzozethrene oligomers with up to 201° end-to-end twist: "one-pot" synthesis and chiral resolution

Twisted polyarenes with persistent chirality are desirable but their synthesis has remained a challenge. In this study, we present a "one-pot" synthesis of 1,2:8,9-dibenzozethrene (DBZ) and its vertically fused dimers and trimers using nickel-catalyzed cyclo-oligomerization reactions. X-ra...

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Bibliographic Details
Main Authors: Sun, Zhitao, Fan, Wei, Han, Yi, Yuan, Wei, Ni, Yong, Wang, Jinyi, Wei, Haipeng, Zhao, Yanli, Sun, Zhe, Wu, Jishan
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Journal Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Chiral Resolutions
Cyclooligomerization
Online Access:https://hdl.handle.net/10356/171753

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