Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production

Efficient energy storage technology is a crucial step in achieving the broad deployment of renewable energies. Thermochemical heat transformer (THT), which rely on reversible gas–solid reactions, can provide an option for efficient energy storage and heat upgrade. In this article, a pressurisation-a...

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Main Authors: Li, Wei, Zhang, Lianjie, Ling, Xiang
Other Authors: School of Mechanical and Aerospace Engineering
Format: Journal Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/172262
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author Li, Wei
Zhang, Lianjie
Ling, Xiang
author2 School of Mechanical and Aerospace Engineering
author_facet School of Mechanical and Aerospace Engineering
Li, Wei
Zhang, Lianjie
Ling, Xiang
author_sort Li, Wei
collection NTU
description Efficient energy storage technology is a crucial step in achieving the broad deployment of renewable energies. Thermochemical heat transformer (THT), which rely on reversible gas–solid reactions, can provide an option for efficient energy storage and heat upgrade. In this article, a pressurisation-assisted sorption THT system driven by low-grade solar thermal energy is proposed to meet the heat demand of domestic hot water (DHW) production, and different temperature rises can be realised by regulating the water vapour pressure. The thermodynamic and economic performances of the THT systems employing ten kinds of salt hydrates are investigated under various operating conditions. The results indicate that most salts-based THT systems enable output temperatures higher than 60 °C. Two-stage pressurisation systems can further elevate the temperature lift but at the cost of thermodynamic performance. SrBr2·6H2O, K2CO3·1.5H2O, and LiOH·H2O are more promising hydrates for the THT system by taking energy density, temperature lift, and thermo-economic performance into account. Compared to the classical TCES cycle, the temperature lifts attained by the above salts-based single-stage and two-stage pressurisation THT systems are 17.6–19.9 °C and 32.2–37.8 °C, respectively. Multi-objective optimisation results suggest that the optimum exergy efficiency for the SrBr2-, K2CO3-, and LiOH-based systems are 82.47%, 55.08%, and 63.97%, and the corresponding levelized energy costs (LECs) are 0.3549, 0.7132, and 0.5721 $/kWh, respectively. The results of this study demonstrate the significant potential of developing such pressurisation-assisted THT system for heat upgradation targeting DHW production.
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spelling ntu-10356/1722622023-12-04T07:21:53Z Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production Li, Wei Zhang, Lianjie Ling, Xiang School of Mechanical and Aerospace Engineering Engineering::Mechanical engineering Pressurisation-Assisted Thermochemical Heat Salt Hydrate Efficient energy storage technology is a crucial step in achieving the broad deployment of renewable energies. Thermochemical heat transformer (THT), which rely on reversible gas–solid reactions, can provide an option for efficient energy storage and heat upgrade. In this article, a pressurisation-assisted sorption THT system driven by low-grade solar thermal energy is proposed to meet the heat demand of domestic hot water (DHW) production, and different temperature rises can be realised by regulating the water vapour pressure. The thermodynamic and economic performances of the THT systems employing ten kinds of salt hydrates are investigated under various operating conditions. The results indicate that most salts-based THT systems enable output temperatures higher than 60 °C. Two-stage pressurisation systems can further elevate the temperature lift but at the cost of thermodynamic performance. SrBr2·6H2O, K2CO3·1.5H2O, and LiOH·H2O are more promising hydrates for the THT system by taking energy density, temperature lift, and thermo-economic performance into account. Compared to the classical TCES cycle, the temperature lifts attained by the above salts-based single-stage and two-stage pressurisation THT systems are 17.6–19.9 °C and 32.2–37.8 °C, respectively. Multi-objective optimisation results suggest that the optimum exergy efficiency for the SrBr2-, K2CO3-, and LiOH-based systems are 82.47%, 55.08%, and 63.97%, and the corresponding levelized energy costs (LECs) are 0.3549, 0.7132, and 0.5721 $/kWh, respectively. The results of this study demonstrate the significant potential of developing such pressurisation-assisted THT system for heat upgradation targeting DHW production. This work was supported by the National Natural Science Foundation of China (No. 52204420) and Natural Science Research of Jiangsu Higher Education Institutions of China (NO. 22KJB480005). 2023-12-04T07:21:53Z 2023-12-04T07:21:53Z 2023 Journal Article Li, W., Zhang, L. & Ling, X. (2023). Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production. Energy Conversion and Management, 277, 116644-. https://dx.doi.org/10.1016/j.enconman.2022.116644 0196-8904 https://hdl.handle.net/10356/172262 10.1016/j.enconman.2022.116644 2-s2.0-85145828039 277 116644 en Energy Conversion and Management © 2022 Elsevier Ltd. All rights reserved.
spellingShingle Engineering::Mechanical engineering
Pressurisation-Assisted Thermochemical Heat
Salt Hydrate
Li, Wei
Zhang, Lianjie
Ling, Xiang
Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title_full Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title_fullStr Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title_full_unstemmed Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title_short Thermo-economic assessment of salt hydrate-based thermochemical heat transformer system: heat upgrade for matching domestic hot water production
title_sort thermo economic assessment of salt hydrate based thermochemical heat transformer system heat upgrade for matching domestic hot water production
topic Engineering::Mechanical engineering
Pressurisation-Assisted Thermochemical Heat
Salt Hydrate
url https://hdl.handle.net/10356/172262
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AT zhanglianjie thermoeconomicassessmentofsalthydratebasedthermochemicalheattransformersystemheatupgradeformatchingdomestichotwaterproduction
AT lingxiang thermoeconomicassessmentofsalthydratebasedthermochemicalheattransformersystemheatupgradeformatchingdomestichotwaterproduction