Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules
Polycyclic aromatic hydrocarbons (PAHs) have gained significant interest for their potential application in various fields. Nitrogen doping in carbon-based materials has been explored to enhance their capabilities. This thesis investigates the advantages of using bifunctional polycyclic azomethin...
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| Format: | Thesis-Doctor of Philosophy |
| Language: | English |
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Nanyang Technological University
2024
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| Online Access: | https://hdl.handle.net/10356/173433 |
| _version_ | 1826130059057954816 |
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| author | Hanindita, Fiona |
| author2 | Shingo Ito |
| author_facet | Shingo Ito Hanindita, Fiona |
| author_sort | Hanindita, Fiona |
| collection | NTU |
| description | Polycyclic aromatic hydrocarbons (PAHs) have gained significant interest for their
potential application in various fields. Nitrogen doping in carbon-based materials has been
explored to enhance their capabilities. This thesis investigates the advantages of using
bifunctional polycyclic azomethine ylides (PAMYs) to synthesize nitrogen-doped PAHs (NPAHs).
Chapter 1 introduces the research background, highlighting the significance of NPAHs
and the role of PAMYs as building blocks. Chapter 2 explores their application in
polymer synthesis and molecular tweezers. Chapter 3 presents a novel diaza[80]fullerene
fragment with extensive π-conjugation using bifunctional PAMYs, exhibiting selective
association towards C120. Chapter 4 focuses on an S-shaped fused azacorannulene dimer with
a C62N2 core, demonstrating a powerful approach to synthesize π-extended polycyclic
aromatic molecules. |
| first_indexed | 2024-10-01T07:50:21Z |
| format | Thesis-Doctor of Philosophy |
| id | ntu-10356/173433 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:50:21Z |
| publishDate | 2024 |
| publisher | Nanyang Technological University |
| record_format | dspace |
| spelling | ntu-10356/1734332024-03-07T08:52:06Z Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules Hanindita, Fiona Shingo Ito School of Chemistry, Chemical Engineering and Biotechnology sgito@ntu.edu.sg Chemistry Polycyclic aromatic hydrocarbons (PAHs) have gained significant interest for their potential application in various fields. Nitrogen doping in carbon-based materials has been explored to enhance their capabilities. This thesis investigates the advantages of using bifunctional polycyclic azomethine ylides (PAMYs) to synthesize nitrogen-doped PAHs (NPAHs). Chapter 1 introduces the research background, highlighting the significance of NPAHs and the role of PAMYs as building blocks. Chapter 2 explores their application in polymer synthesis and molecular tweezers. Chapter 3 presents a novel diaza[80]fullerene fragment with extensive π-conjugation using bifunctional PAMYs, exhibiting selective association towards C120. Chapter 4 focuses on an S-shaped fused azacorannulene dimer with a C62N2 core, demonstrating a powerful approach to synthesize π-extended polycyclic aromatic molecules. Doctor of Philosophy 2024-02-05T07:45:30Z 2024-02-05T07:45:30Z 2024 Thesis-Doctor of Philosophy Hanindita, F. (2024). Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/173433 https://hdl.handle.net/10356/173433 10.32657/10356/173433 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
| spellingShingle | Chemistry Hanindita, Fiona Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title | Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title_full | Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title_fullStr | Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title_full_unstemmed | Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title_short | Bifunctional polycyclic azomethine ylides: a building block to Pi-extended aromatic molecules |
| title_sort | bifunctional polycyclic azomethine ylides a building block to pi extended aromatic molecules |
| topic | Chemistry |
| url | https://hdl.handle.net/10356/173433 |
| work_keys_str_mv | AT haninditafiona bifunctionalpolycyclicazomethineylidesabuildingblocktopiextendedaromaticmolecules |