Carbene- and photocatalysis redefine arene acylation

Carbene- and photocatalysis redefine arene acylation

Combined N-heterocyclic carbene and photoredox-catalysed strategies for the acylation of arenes offer regiocontrol that is complementary to Lewis-acid-mediated Friedel–Crafts approaches.

Bibliographic Details
Main Authors:	Song, Runjiang, Ren, Shichao, Chi, Robin Yonggui
Other Authors:	School of Chemistry, Chemical Engineering and Biotechnology
Format:	Journal Article
Language:	English
Published:	2024
Subjects:	Chemistry Arene Acylation Carbene- and Photocatalysis
Online Access:	https://hdl.handle.net/10356/173450

Similar Items

Carbene-catalyzed alkylation of carboxylic esters via direct photoexcitation of acyl azolium intermediates
by: Ren, Shi-Cao, et al.
Published: (2021)

N-heterocyclic carbene-catalyzed arene formation reactions
by: Li, Tingting, et al.
Published: (2022)

N-Heterocyclic carbene catalyzed radical coupling of aldehydes with redox-active esters
by: Song, Runjiang, et al.
Published: (2020)

Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones
by: Ren, Shi-Chao, et al.
Published: (2022)

Pd(II)-Catalyzed C-H Acylation of (Hetero)arenes—Recent Advances
by: Carlos Santiago, et al.
Published: (2020-07-01)

Carbene-catalyzed α,γ-deuteration of enals under oxidative conditions
by: Zhang, Xiaolei, et al.
Published: (2021)

Carbene organic catalytic planar enantioselective macrolactonization
by: Lv, Xiaokang, et al.
Published: (2024)

Carbene-catalyzed enantioselective addition of benzylic carbon to unsaturated acyl azolium for rapid synthesis of pyrrolo[3,2- c]quinolines
by: Wang, Jilan, et al.
Published: (2020)

Asymmetric reactions of N-heterocyclic carbene (NHC)-based chiral acyl azoliums and azolium enolates
by: Changgui Zhao, et al.
Published: (2021-05-01)

N-Heterocyclic carbene-catalyzed remote enantioselective C-C bond formation via 1,6-addition with formyl enynes
by: Peng, Xiaolin, et al.
Published: (2024)

N-Heterocyclic carbene organocatalysis : activation modes and typical reactive intermediates
by: Chen, Xingkuan, et al.
Published: (2022)

Carbene-catalyzed access to thiochromene derivatives: control of reaction pathways via slow release of thiols from disulfides
by: Wu, Qifei, et al.
Published: (2023)

Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes
by: Wu, Xingxing, et al.
Published: (2017)

A Review on Generation and Reactivity of the <i>N</i>-Heterocyclic Carbene-Bound Alkynyl Acyl Azolium Intermediates
by: Ziyang Dong, et al.
Published: (2022-11-01)

Carbene-catalyzed indole 3-Methyl C(sp3)-H bond functionalization
by: Cheng, Jian, et al.
Published: (2020)

Carbene-catalyzed enantioselective addition of thioamides to bromoenals for access to thiazinone heterocycles
by: Liu, Changyi, et al.
Published: (2020)

Carbene-catalyzed direct functionalization of the β-sp3 -carbon atoms of α-chloroaldehydes
by: Liu, Bin, et al.
Published: (2020)

Carbene-catalyzed [4 + 2] cycloadditions of vinyl enolate and (in situ generated) imines for enantioselective synthesis of quaternary α-amino phosphonates
by: Sun, Jun, et al.
Published: (2020)

Carbene-catalyzed formal [3+3] cycloaddition reaction for access to substituted 2-phenylbenzothiazoles
by: Ni, Zhibin, et al.
Published: (2020)

Carbenes/
by: Jones, Maitland, et al.
Published: (1973)

N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
by: Lv, Jie, et al.
Published: (2023)

Carbene-catalyzed α-carbon amination of chloroaldehydes for enantioselective access to dihydroquinoxaline derivatives
by: Huang, Ruoyan, et al.
Published: (2020)

A reaction mode of carbene-catalysed aryl aldehyde activation and induced phenol OH functionalization
by: Chen, Xingkuan, et al.
Published: (2018)

Enantio- and diastereoselective synthesis of chromeno[4,3-b]pyrrole derivatives bearing tetrasubstituted chirality centers through carbene catalyzed cascade reactions
by: Li, Tingting, et al.
Published: (2020)

Addition of a carbene catalyst to indole aryl aldehyde activates a remote δ-sp2 carbon for protonation and formal [4+2] reaction
by: Zheng, Pengcheng, et al.
Published: (2020)

Carbene-Catalyzed Dynamic Kinetic Resolution of Carboxylic Esters
by: Chen, Xingkuan, et al.
Published: (2017)

Carbene-catalyzed enantioselective oxidative coupling of enals and di(hetero)arylmethanes
by: Chen, Qiao, et al.
Published: (2019)

Enantioselective indole N-H functionalization enabled by addition of carbene catalyst to indole aldehyde at remote site
by: Yang, Xing, et al.
Published: (2020)

Carbene-catalyzed dynamic kinetic resolution and asymmetric acylation of hydroxyphthalides and related natural products
by: Liu, Yingguo, et al.
Published: (2020)

Access to planar chiral ferrocenes via N-heterocyclic carbene-catalyzed enantioselective desymmetrization reactions
by: Lv, Xiaokang, et al.
Published: (2022)

Carbene-catalyzed enantioselective aldol reaction : post-aldol stereochemistry control and formation of quaternary stereogenic centers
by: Yang, Xing, et al.
Published: (2021)

Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis
by: Amrita Das, et al.
Published: (2018-09-01)

N-heterocyclic carbenes : from laboratory curiosities to efficient synthetic tools /
by: Diez-Gonzalez, Silvia
Published: (2011)

Carbene-catalyzed asymmetric construction of atropisomers
by: Song, Runjiang, et al.
Published: (2022)

Palladium-Catalyzed Room Temperature Acylative Cross-Coupling of Activated Amides with Trialkylboranes
by: Weijia Shi, et al.
Published: (2018-09-01)

Carbene-catalyzed desymmetrization of 1,3-diols: access to optically enriched tertiary alkyl chlorides
by: Li, Bao-Sheng, et al.
Published: (2017)

Theoretical Study of N-Heterocyclic-Carbene–ZnX<sub>2</sub> (X = H, Me, Et) Complexes
by: Mirosław Jabłoński
Published: (2021-10-01)

Visible-Light-Induced Difunctionalization of the C-C Bond of Alkylidenecyclopropanes with Acyl Chlorides
by: Chuan Ding, et al.
Published: (2023-05-01)

Iridium/N-heterocyclic carbene-catalyzed C–H borylation of arenes by diisopropylaminoborane
by: Mamoru Tobisu, et al.
Published: (2016-04-01)

Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis, Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction
by: Lara Hettmanczyk, et al.
Published: (2016-11-01)