Mini-review on the novel synthesis and potential applications of carbazole and its derivatives
Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages of synthetic diversity, chemical and physical stability, microporous size controllability, etc. MOPs indicate broad applications in various fields such as heterogeneous catalysis, gas adsorption, separation...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Language: | English |
| Published: |
2024
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| Online Access: | https://hdl.handle.net/10356/173660 |
| _version_ | 1811680910168293376 |
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| author | Xu, Zhichao Wu, Di Fang, Cong Li, Yuanzhe |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Xu, Zhichao Wu, Di Fang, Cong Li, Yuanzhe |
| author_sort | Xu, Zhichao |
| collection | NTU |
| description | Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages of synthetic diversity, chemical and physical stability, microporous size controllability, etc. MOPs indicate broad applications in various fields such as heterogeneous catalysis, gas adsorption, separation, and storage. In recent years, MOPs have attracted an enormous attention in greenhouse gas capture due to their great potential in physisorptive gas storage. Carbazole and its derivatives have been studied extensively as Metal-Organic Polyhedra (MOPs) building blocks due to their unique structural features and versatile functionalization possibilities. This paper systematically reviews the synthesis, characterization and application of carbazole-based polymers, and relationship of structures and properties of these polymers. The application of the polymers in carbon dioxide (CO2) capture field is analysed taking advantage of their adjustable microporous structure and electron rich properties. This review also provides novel insights regarding functional polymer materials that have high ability of greenhouse gas capture and absorbing selectivity will be obtained by reasonable molecular design and efficient synthesis. |
| first_indexed | 2024-10-01T03:32:33Z |
| format | Journal Article |
| id | ntu-10356/173660 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:32:33Z |
| publishDate | 2024 |
| record_format | dspace |
| spelling | ntu-10356/1736602024-02-23T15:45:30Z Mini-review on the novel synthesis and potential applications of carbazole and its derivatives Xu, Zhichao Wu, Di Fang, Cong Li, Yuanzhe School of Materials Science and Engineering Engineering Carbazole Microporous organic polymers Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages of synthetic diversity, chemical and physical stability, microporous size controllability, etc. MOPs indicate broad applications in various fields such as heterogeneous catalysis, gas adsorption, separation, and storage. In recent years, MOPs have attracted an enormous attention in greenhouse gas capture due to their great potential in physisorptive gas storage. Carbazole and its derivatives have been studied extensively as Metal-Organic Polyhedra (MOPs) building blocks due to their unique structural features and versatile functionalization possibilities. This paper systematically reviews the synthesis, characterization and application of carbazole-based polymers, and relationship of structures and properties of these polymers. The application of the polymers in carbon dioxide (CO2) capture field is analysed taking advantage of their adjustable microporous structure and electron rich properties. This review also provides novel insights regarding functional polymer materials that have high ability of greenhouse gas capture and absorbing selectivity will be obtained by reasonable molecular design and efficient synthesis. Published version This work was supported by the National Natural Science Foundation of China (Grant number 51704258); the research foundation of Zhuzhou Smelter Group Co (Grant number ZYKJ20190422002); and the Natural science foundation of Hunan Province, China (Grant number 2019JJ50587). 2024-02-21T04:31:59Z 2024-02-21T04:31:59Z 2023 Journal Article Xu, Z., Wu, D., Fang, C. & Li, Y. (2023). Mini-review on the novel synthesis and potential applications of carbazole and its derivatives. Designed Monomers and Polymers, 26(1), 90-105. https://dx.doi.org/10.1080/15685551.2023.2194174 1568-5551 https://hdl.handle.net/10356/173660 10.1080/15685551.2023.2194174 37008385 2-s2.0-85152452189 1 26 90 105 en Designed Monomers and Polymers © 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The terms on which this article has been published allow the posting of the Accepted Manuscript in a repository by the author(s) or with their consent. application/pdf |
| spellingShingle | Engineering Carbazole Microporous organic polymers Xu, Zhichao Wu, Di Fang, Cong Li, Yuanzhe Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title | Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title_full | Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title_fullStr | Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title_full_unstemmed | Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title_short | Mini-review on the novel synthesis and potential applications of carbazole and its derivatives |
| title_sort | mini review on the novel synthesis and potential applications of carbazole and its derivatives |
| topic | Engineering Carbazole Microporous organic polymers |
| url | https://hdl.handle.net/10356/173660 |
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