Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane

The insertion of carbon monoxide (CO) into an unsymmetrical diborene, concomitant with B-O bond formation under ambient conditions, gives an oxaborirane species. A similar insertion reaction with isocyanide, the isoelectronic species of CO, generates azaboriridine derivatives.

Bibliographic Details
Main Authors: Zhu, Lizhao, Kinjo, Rei
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Journal Article
Language:English
Published: 2024
Subjects:
Online Access:https://hdl.handle.net/10356/174233
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author Zhu, Lizhao
Kinjo, Rei
author2 School of Chemistry, Chemical Engineering and Biotechnology
author_facet School of Chemistry, Chemical Engineering and Biotechnology
Zhu, Lizhao
Kinjo, Rei
author_sort Zhu, Lizhao
collection NTU
description The insertion of carbon monoxide (CO) into an unsymmetrical diborene, concomitant with B-O bond formation under ambient conditions, gives an oxaborirane species. A similar insertion reaction with isocyanide, the isoelectronic species of CO, generates azaboriridine derivatives.
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spelling ntu-10356/1742332024-03-22T15:31:40Z Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane Zhu, Lizhao Kinjo, Rei School of Chemistry, Chemical Engineering and Biotechnology Chemistry Azaboriridine derivative Carbon monoxide The insertion of carbon monoxide (CO) into an unsymmetrical diborene, concomitant with B-O bond formation under ambient conditions, gives an oxaborirane species. A similar insertion reaction with isocyanide, the isoelectronic species of CO, generates azaboriridine derivatives. National Research Foundation (NRF) Submitted/Accepted version We are grateful to Nanyang Technological University (NTU), Nippon Shokubai, and the National Research Foundation, Singapore (NRF-NRFI07-2021-0002) for financial support. 2024-03-22T05:22:29Z 2024-03-22T05:22:29Z 2023 Journal Article Zhu, L. & Kinjo, R. (2023). Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane. Chemical Communications, 59(69), 10436-10439. https://dx.doi.org/10.1039/d3cc02844e 1359-7345 https://hdl.handle.net/10356/174233 10.1039/d3cc02844e 37555354 2-s2.0-85168743371 69 59 10436 10439 en NRF-NRFI07-2021-0002 Chemical Communications © 2023 The Author(s). All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1039/D3CC02844E. application/pdf
spellingShingle Chemistry
Azaboriridine derivative
Carbon monoxide
Zhu, Lizhao
Kinjo, Rei
Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title_full Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title_fullStr Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title_full_unstemmed Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title_short Insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
title_sort insertion of carbon monoxide into an unsymmetrical diborene to form an oxaborirane
topic Chemistry
Azaboriridine derivative
Carbon monoxide
url https://hdl.handle.net/10356/174233
work_keys_str_mv AT zhulizhao insertionofcarbonmonoxideintoanunsymmetricaldiborenetoformanoxaborirane
AT kinjorei insertionofcarbonmonoxideintoanunsymmetricaldiborenetoformanoxaborirane