Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets
Recently, transition-metal phosphides have emerged as favorable electrocatalysts for facilitating oxygen evolution reactions (OERs). This study successfully synthesized a heterostructure comprising interconnected ultrathin nanosheet arrays of CoxP grown on nickel foam (NF) through electrodeposition...
| Main Authors: | , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2024
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/180169 |
| _version_ | 1826111111525564416 |
|---|---|
| author | Kolaei, Morteza Chavan, Harish S. Kim, Jiyoung Lee, Kiyoung |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Kolaei, Morteza Chavan, Harish S. Kim, Jiyoung Lee, Kiyoung |
| author_sort | Kolaei, Morteza |
| collection | NTU |
| description | Recently, transition-metal phosphides have emerged as favorable electrocatalysts for facilitating oxygen evolution reactions (OERs). This study successfully synthesized a heterostructure comprising interconnected ultrathin nanosheet arrays of CoxP grown on nickel foam (NF) through electrodeposition and phosphorization processes. Subsequently, a layer of CoFe layered double hydroxides (LDH) was electrodeposited onto the CoxP/NF substrate, resulting in the formation of the heterostructure CoxP@CoFe-LDH. The OER efficiency of the CoxP nanosheets exhibited substantial improvement because of the more accessible active sites and faster electron transfer capability of the heterostructure system. This improvement can be attributed to the higher surface area and well-established interfacial coupling between the ultrathin nanosheets of CoxP and CoFe-LDH. Consequently, the CoxP6@CoFe2/NF anode displays remarkable performance in enabling OERs, requiring merely a minimal overpotential of 230 mV at a current density of 10 mA·cm−2 in 1 M KOH. This result signifies a substantial improvement when compared to the performance of the bare CoxP and CoFe-LDH samples. Moreover, the heterostructure system enhanced the structural durability during the OERs, leading to remarkable stability over a continuous operation period of 50 h. |
| first_indexed | 2024-10-01T02:45:17Z |
| format | Journal Article |
| id | ntu-10356/180169 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:45:17Z |
| publishDate | 2024 |
| record_format | dspace |
| spelling | ntu-10356/1801692024-09-23T01:31:01Z Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets Kolaei, Morteza Chavan, Harish S. Kim, Jiyoung Lee, Kiyoung School of Chemical and Biomedical Engineering Cambridge Centre for Advanced Research and Education in Singapore Engineering Electrocatalysts Oxygen evolution reaction Recently, transition-metal phosphides have emerged as favorable electrocatalysts for facilitating oxygen evolution reactions (OERs). This study successfully synthesized a heterostructure comprising interconnected ultrathin nanosheet arrays of CoxP grown on nickel foam (NF) through electrodeposition and phosphorization processes. Subsequently, a layer of CoFe layered double hydroxides (LDH) was electrodeposited onto the CoxP/NF substrate, resulting in the formation of the heterostructure CoxP@CoFe-LDH. The OER efficiency of the CoxP nanosheets exhibited substantial improvement because of the more accessible active sites and faster electron transfer capability of the heterostructure system. This improvement can be attributed to the higher surface area and well-established interfacial coupling between the ultrathin nanosheets of CoxP and CoFe-LDH. Consequently, the CoxP6@CoFe2/NF anode displays remarkable performance in enabling OERs, requiring merely a minimal overpotential of 230 mV at a current density of 10 mA·cm−2 in 1 M KOH. This result signifies a substantial improvement when compared to the performance of the bare CoxP and CoFe-LDH samples. Moreover, the heterostructure system enhanced the structural durability during the OERs, leading to remarkable stability over a continuous operation period of 50 h. 2024-09-23T01:31:01Z 2024-09-23T01:31:01Z 2024 Journal Article Kolaei, M., Chavan, H. S., Kim, J. & Lee, K. (2024). Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 689, 133640-. https://dx.doi.org/10.1016/j.colsurfa.2024.133640 0927-7757 https://hdl.handle.net/10356/180169 10.1016/j.colsurfa.2024.133640 2-s2.0-85187787818 689 133640 en Colloids and Surfaces A: Physicochemical and Engineering Aspects © 2024 Elsevier B.V. All rights reserved. |
| spellingShingle | Engineering Electrocatalysts Oxygen evolution reaction Kolaei, Morteza Chavan, Harish S. Kim, Jiyoung Lee, Kiyoung Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title | Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title_full | Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title_fullStr | Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title_full_unstemmed | Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title_short | Enhancing oxygen evolution reaction of CoP nanosheets via interfacial engineering with CoFe-LDH nanosheets |
| title_sort | enhancing oxygen evolution reaction of cop nanosheets via interfacial engineering with cofe ldh nanosheets |
| topic | Engineering Electrocatalysts Oxygen evolution reaction |
| url | https://hdl.handle.net/10356/180169 |
| work_keys_str_mv | AT kolaeimorteza enhancingoxygenevolutionreactionofcopnanosheetsviainterfacialengineeringwithcofeldhnanosheets AT chavanharishs enhancingoxygenevolutionreactionofcopnanosheetsviainterfacialengineeringwithcofeldhnanosheets AT kimjiyoung enhancingoxygenevolutionreactionofcopnanosheetsviainterfacialengineeringwithcofeldhnanosheets AT leekiyoung enhancingoxygenevolutionreactionofcopnanosheetsviainterfacialengineeringwithcofeldhnanosheets |