Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material

Extraterrestrial exploration, represented by Lunar base construction, has been promoted worldwide as a multi-disciplinary, cutting-edge and strategic issue. Herein we proposed a novel extraterrestrial construction material composed of Lunar/Martian regolith simulants and only 4 wt% of silicate adhes...

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Main Authors: Geng, Zifan., Zhang, Lizhi, Wu, Zhiwen, Huang, Jiale, Wang, Xiangyu, Tan, Ming Jen, She, Wei, Zhou, Hao, Geng, Guoqing
Other Authors: School of Mechanical and Aerospace Engineering
Format: Journal Article
Language:English
Published: 2024
Subjects:
Online Access:https://hdl.handle.net/10356/180775
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author Geng, Zifan.
Zhang, Lizhi
Wu, Zhiwen
Huang, Jiale
Wang, Xiangyu
Tan, Ming Jen
She, Wei
Zhou, Hao
Geng, Guoqing
author2 School of Mechanical and Aerospace Engineering
author_facet School of Mechanical and Aerospace Engineering
Geng, Zifan.
Zhang, Lizhi
Wu, Zhiwen
Huang, Jiale
Wang, Xiangyu
Tan, Ming Jen
She, Wei
Zhou, Hao
Geng, Guoqing
author_sort Geng, Zifan.
collection NTU
description Extraterrestrial exploration, represented by Lunar base construction, has been promoted worldwide as a multi-disciplinary, cutting-edge and strategic issue. Herein we proposed a novel extraterrestrial construction material composed of Lunar/Martian regolith simulants and only 4 wt% of silicate adhesive. This silicate-regolith composite can be directly self-hardened in vacuum within 4.5 h without any curing to achieve 29 MPa of hardening strength. Meanwhile, it shows comprehensive durability with stable microstructures and >70 % of residual strength against long-term vacuum exposure, huge temperature difference and intense γ-ray and proton radiations. Its in-situ solidification and durability originate from vacuum dehydration, where silica clusters in solution spontaneously cohere into a solid network with strong connections of silica tetrahedra and bound water. A moderate silicate modulus around 2.5 and appropriate modifications can disperse finer silica clusters to increase oligomer silica units in solution and enhance hardening strength. Compared with lunar geopolymer and other existing extraterrestrial construction materials, this vacuum self-hardening composite allows a cryogenic preparation even below −40 ℃ using diverse regolith with a wide range of compositions and sizes, proposing a facile, durable and versatile solution towards in-situ extraterrestrial constructions.
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spelling ntu-10356/1807752024-10-23T08:06:06Z Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material Geng, Zifan. Zhang, Lizhi Wu, Zhiwen Huang, Jiale Wang, Xiangyu Tan, Ming Jen She, Wei Zhou, Hao Geng, Guoqing School of Mechanical and Aerospace Engineering Singapore Centre for 3D Printing Engineering Extraterrestrial construction Lunar regolith Extraterrestrial exploration, represented by Lunar base construction, has been promoted worldwide as a multi-disciplinary, cutting-edge and strategic issue. Herein we proposed a novel extraterrestrial construction material composed of Lunar/Martian regolith simulants and only 4 wt% of silicate adhesive. This silicate-regolith composite can be directly self-hardened in vacuum within 4.5 h without any curing to achieve 29 MPa of hardening strength. Meanwhile, it shows comprehensive durability with stable microstructures and >70 % of residual strength against long-term vacuum exposure, huge temperature difference and intense γ-ray and proton radiations. Its in-situ solidification and durability originate from vacuum dehydration, where silica clusters in solution spontaneously cohere into a solid network with strong connections of silica tetrahedra and bound water. A moderate silicate modulus around 2.5 and appropriate modifications can disperse finer silica clusters to increase oligomer silica units in solution and enhance hardening strength. Compared with lunar geopolymer and other existing extraterrestrial construction materials, this vacuum self-hardening composite allows a cryogenic preparation even below −40 ℃ using diverse regolith with a wide range of compositions and sizes, proposing a facile, durable and versatile solution towards in-situ extraterrestrial constructions. The authors gratefully acknowledge the financial support from the National Key Research and Development Program of China [grant: 2021YFF0500300]; the Postgraduate Research & Practice Innovation Program of Jiangsu Province [grant: KYCX23_0235] and the State Scholarship Fund of China Scholarship Council [grant: 202206090145]. 2024-10-23T07:59:01Z 2024-10-23T07:59:01Z 2024 Journal Article Geng, Z., Zhang, L., Wu, Z., Huang, J., Wang, X., Tan, M. J., She, W., Zhou, H. & Geng, G. (2024). Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material. Construction and Building Materials, 449, 138517-. https://dx.doi.org/10.1016/j.conbuildmat.2024.138517 0950-0618 https://hdl.handle.net/10356/180775 10.1016/j.conbuildmat.2024.138517 2-s2.0-85204980083 449 138517 en Construction and Building Materials © 2024 Elsevier Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies.
spellingShingle Engineering
Extraterrestrial construction
Lunar regolith
Geng, Zifan.
Zhang, Lizhi
Wu, Zhiwen
Huang, Jiale
Wang, Xiangyu
Tan, Ming Jen
She, Wei
Zhou, Hao
Geng, Guoqing
Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title_full Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title_fullStr Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title_full_unstemmed Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title_short Silicate-lunar regolith composite: a vacuum self-hardened and comprehensively durable extraterrestrial construction material
title_sort silicate lunar regolith composite a vacuum self hardened and comprehensively durable extraterrestrial construction material
topic Engineering
Extraterrestrial construction
Lunar regolith
url https://hdl.handle.net/10356/180775
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