Design and optimization of thin film organic solar cells

The aim of this Ph.D. project was to undertake a systematic study to develop a technique for improving the performance of solution-processed translucent P3HT:PCBM-based solar cells over the two competing indexes: power conversion efficiency and transmittance, for stacking up or transparency. A compr...

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Bibliographic Details
Main Author: Ng, Ging Meng
Other Authors: Zhu Furong
Format: Thesis
Language:English
Published: 2009
Subjects:
Online Access:https://hdl.handle.net/10356/18707
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author Ng, Ging Meng
author2 Zhu Furong
author_facet Zhu Furong
Ng, Ging Meng
author_sort Ng, Ging Meng
collection NTU
description The aim of this Ph.D. project was to undertake a systematic study to develop a technique for improving the performance of solution-processed translucent P3HT:PCBM-based solar cells over the two competing indexes: power conversion efficiency and transmittance, for stacking up or transparency. A comprehensive optical admittance analysis was applied to study the optical properties of conventional opaque and translucent P3HT:PCBM-based PSCs. The simulation uses the dispersive refractive index n(λ) and extinction coefficient k(λ) of P3HT:PCBM blend and other functional layers that were measured by VASE to calculate the optical absorbance and transmittance of P3HT:PCBM-based PSCs. The optimal device structure was obtained by maximizing the light absorption of the active layer (P3HT:PCBM) and the transmission of the whole translucent PSCs. AFM was used to examine the surface roughness of the P3HT:PCBM film prepared in this work. Based on the optimal device parameters derived from the simulation, a 60 nm thick ITO was found to be optimal and was used to fabricate the translucent PSCs with the structure of glass/ITO/PEDOT:PSS/P3HT:PCBM(75nm)/Ca(10nm)/ Ag(10nm)/ITO(60 nm).
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spelling ntu-10356/187072023-03-04T16:39:33Z Design and optimization of thin film organic solar cells Ng, Ging Meng Zhu Furong School of Materials Science & Engineering DRNTU::Engineering::Materials::Organic/Polymer electronics The aim of this Ph.D. project was to undertake a systematic study to develop a technique for improving the performance of solution-processed translucent P3HT:PCBM-based solar cells over the two competing indexes: power conversion efficiency and transmittance, for stacking up or transparency. A comprehensive optical admittance analysis was applied to study the optical properties of conventional opaque and translucent P3HT:PCBM-based PSCs. The simulation uses the dispersive refractive index n(λ) and extinction coefficient k(λ) of P3HT:PCBM blend and other functional layers that were measured by VASE to calculate the optical absorbance and transmittance of P3HT:PCBM-based PSCs. The optimal device structure was obtained by maximizing the light absorption of the active layer (P3HT:PCBM) and the transmission of the whole translucent PSCs. AFM was used to examine the surface roughness of the P3HT:PCBM film prepared in this work. Based on the optimal device parameters derived from the simulation, a 60 nm thick ITO was found to be optimal and was used to fabricate the translucent PSCs with the structure of glass/ITO/PEDOT:PSS/P3HT:PCBM(75nm)/Ca(10nm)/ Ag(10nm)/ITO(60 nm). DOCTOR OF PHILOSOPHY (SME) 2009-07-06T01:30:48Z 2009-07-06T01:30:48Z 2009 2009 Thesis Ng, G. M. (2009). Design and optimization of thin film organic solar cells. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/18707 10.32657/10356/18707 en 144 p. application/pdf
spellingShingle DRNTU::Engineering::Materials::Organic/Polymer electronics
Ng, Ging Meng
Design and optimization of thin film organic solar cells
title Design and optimization of thin film organic solar cells
title_full Design and optimization of thin film organic solar cells
title_fullStr Design and optimization of thin film organic solar cells
title_full_unstemmed Design and optimization of thin film organic solar cells
title_short Design and optimization of thin film organic solar cells
title_sort design and optimization of thin film organic solar cells
topic DRNTU::Engineering::Materials::Organic/Polymer electronics
url https://hdl.handle.net/10356/18707
work_keys_str_mv AT nggingmeng designandoptimizationofthinfilmorganicsolarcells