Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79...
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
2009
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/20676 |
| _version_ | 1824453613335871488 |
|---|---|
| author | Lim, Maricar Bungabong |
| author2 | Leung Pak Hing |
| author_facet | Leung Pak Hing Lim, Maricar Bungabong |
| author_sort | Lim, Maricar Bungabong |
| collection | NTU |
| description | The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is
used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and
DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80
is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide. |
| first_indexed | 2025-02-19T03:09:12Z |
| format | Thesis |
| id | ntu-10356/20676 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:09:12Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | ntu-10356/206762023-02-28T23:57:05Z Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes Lim, Maricar Bungabong Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide. DOCTOR OF PHILOSOPHY (SPMS) 2009-12-23T05:57:19Z 2009-12-23T05:57:19Z 2008 2008 Thesis Lim, M. B. (2008). Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/20676 10.32657/10356/20676 en 283 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Lim, Maricar Bungabong Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title | Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title_full | Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title_fullStr | Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title_full_unstemmed | Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title_short | Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| title_sort | asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/20676 |
| work_keys_str_mv | AT limmaricarbungabong asymmetricsynthesisofchiralarsineligandspromotedbyorganopalladiumcomplexes |