Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79...
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| Format: | Thesis |
| Language: | English |
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2009
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| Online Access: | https://hdl.handle.net/10356/20676 |