Solution processable single-walled carbon nanotubes based thin film field-effect transistors

Single-walled nanotubes (SWNTs) has a unique varying band gap make them one of the choices for fabricating high-performance thin film field-effect transistors by dispersing SWNTs in array to form the conducting channel. The substrate surface plays an important role in solution processable thin film...

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Bibliographic Details
Main Author: Chen, Simin.
Other Authors: Li Lain-Jong
Format: Final Year Project (FYP)
Language:English
Published: 2010
Subjects:
Online Access:http://hdl.handle.net/10356/36188
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author Chen, Simin.
author2 Li Lain-Jong
author_facet Li Lain-Jong
Chen, Simin.
author_sort Chen, Simin.
collection NTU
description Single-walled nanotubes (SWNTs) has a unique varying band gap make them one of the choices for fabricating high-performance thin film field-effect transistors by dispersing SWNTs in array to form the conducting channel. The substrate surface plays an important role in solution processable thin film transistors to selectively interact with semiconducting SWNTs in order to obtain better electrical properties. In this work, the surfaces of silicon thermal oxide were functionalized with silanes before SWNTs suspension drop casting. It was found that dip coating in 1% silane-methanol solution followed by baking can provide clean surface with better properties. The functional groups in silanes were suspected to affect the interaction with SWNTs greatly indicated by different electrical properties obtained. Other factors including SWNTs solution and transistor channel configurations also collaborated in providing certain transistor properties. In addition, a thin layer of polymethyl-methacrylate (PMMA) was found to improve performance regardless of silanes functionalized groups, the on/off ratio achieved was up to 6 orders of magnitude and the mobility could be as high as 15.6 cm2/Vs.
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spelling ntu-10356/361882023-03-04T15:33:15Z Solution processable single-walled carbon nanotubes based thin film field-effect transistors Chen, Simin. Li Lain-Jong School of Materials Science and Engineering DRNTU::Engineering Single-walled nanotubes (SWNTs) has a unique varying band gap make them one of the choices for fabricating high-performance thin film field-effect transistors by dispersing SWNTs in array to form the conducting channel. The substrate surface plays an important role in solution processable thin film transistors to selectively interact with semiconducting SWNTs in order to obtain better electrical properties. In this work, the surfaces of silicon thermal oxide were functionalized with silanes before SWNTs suspension drop casting. It was found that dip coating in 1% silane-methanol solution followed by baking can provide clean surface with better properties. The functional groups in silanes were suspected to affect the interaction with SWNTs greatly indicated by different electrical properties obtained. Other factors including SWNTs solution and transistor channel configurations also collaborated in providing certain transistor properties. In addition, a thin layer of polymethyl-methacrylate (PMMA) was found to improve performance regardless of silanes functionalized groups, the on/off ratio achieved was up to 6 orders of magnitude and the mobility could be as high as 15.6 cm2/Vs. Bachelor of Engineering (Materials Engineering) 2010-04-23T05:57:43Z 2010-04-23T05:57:43Z 2010 2010 Final Year Project (FYP) http://hdl.handle.net/10356/36188 en Nanyang Technological University 53 p. application/pdf
spellingShingle DRNTU::Engineering
Chen, Simin.
Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title_full Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title_fullStr Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title_full_unstemmed Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title_short Solution processable single-walled carbon nanotubes based thin film field-effect transistors
title_sort solution processable single walled carbon nanotubes based thin film field effect transistors
topic DRNTU::Engineering
url http://hdl.handle.net/10356/36188
work_keys_str_mv AT chensimin solutionprocessablesinglewalledcarbonnanotubesbasedthinfilmfieldeffecttransistors