Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity wa...
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Format: | Final Year Project (FYP) |
Language: | English |
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2010
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Online Access: | http://hdl.handle.net/10356/38937 |
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author | Wang, Ya Wen. |
author2 | Chen Hongyu |
author_facet | Chen Hongyu Wang, Ya Wen. |
author_sort | Wang, Ya Wen. |
collection | NTU |
description | A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity was studied, with detailed investigation of the each step in this simple one-pot manner synthesis. The structure was believed to form by the assembly of polymer on the nano-scale template made of electrolytes, followed by the structure deformation caused by surface tension upon water addition. The generality of the methodology was also performed with a variety of different electrolytes and solvent systems. |
first_indexed | 2024-10-01T06:34:51Z |
format | Final Year Project (FYP) |
id | ntu-10356/38937 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T06:34:51Z |
publishDate | 2010 |
record_format | dspace |
spelling | ntu-10356/389372023-02-28T23:16:28Z Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. Wang, Ya Wen. Chen Hongyu School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity was studied, with detailed investigation of the each step in this simple one-pot manner synthesis. The structure was believed to form by the assembly of polymer on the nano-scale template made of electrolytes, followed by the structure deformation caused by surface tension upon water addition. The generality of the methodology was also performed with a variety of different electrolytes and solvent systems. Bachelor of Science in Chemistry and Biological Chemistry 2010-05-21T02:00:27Z 2010-05-21T02:00:27Z 2010 2010 Final Year Project (FYP) http://hdl.handle.net/10356/38937 en 23 p. application/pdf |
spellingShingle | DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry Wang, Ya Wen. Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title | Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title_full | Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title_fullStr | Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title_full_unstemmed | Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title_short | Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. |
title_sort | creating openings in vesicle like polymer nanocavities via templates of nano scale salt crystals |
topic | DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry |
url | http://hdl.handle.net/10356/38937 |
work_keys_str_mv | AT wangyawen creatingopeningsinvesiclelikepolymernanocavitiesviatemplatesofnanoscalesaltcrystals |