Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.

A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity wa...

Full description

Bibliographic Details
Main Author: Wang, Ya Wen.
Other Authors: Chen Hongyu
Format: Final Year Project (FYP)
Language:English
Published: 2010
Subjects:
Online Access:http://hdl.handle.net/10356/38937
_version_ 1826125328744972288
author Wang, Ya Wen.
author2 Chen Hongyu
author_facet Chen Hongyu
Wang, Ya Wen.
author_sort Wang, Ya Wen.
collection NTU
description A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity was studied, with detailed investigation of the each step in this simple one-pot manner synthesis. The structure was believed to form by the assembly of polymer on the nano-scale template made of electrolytes, followed by the structure deformation caused by surface tension upon water addition. The generality of the methodology was also performed with a variety of different electrolytes and solvent systems.
first_indexed 2024-10-01T06:34:51Z
format Final Year Project (FYP)
id ntu-10356/38937
institution Nanyang Technological University
language English
last_indexed 2024-10-01T06:34:51Z
publishDate 2010
record_format dspace
spelling ntu-10356/389372023-02-28T23:16:28Z Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals. Wang, Ya Wen. Chen Hongyu School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry A novel synthesis of a vesicle-like polymer nanocavity which has an opening on the bi-layer shell was achieved with "crew-cut" amphiphilic diblock copolymer PS404-b-PAA62 in an N, N-dimethylformamide (DMF)-H2O-electrolyte ternary system. The mechanism of the formation of this nanocavity was studied, with detailed investigation of the each step in this simple one-pot manner synthesis. The structure was believed to form by the assembly of polymer on the nano-scale template made of electrolytes, followed by the structure deformation caused by surface tension upon water addition. The generality of the methodology was also performed with a variety of different electrolytes and solvent systems. Bachelor of Science in Chemistry and Biological Chemistry 2010-05-21T02:00:27Z 2010-05-21T02:00:27Z 2010 2010 Final Year Project (FYP) http://hdl.handle.net/10356/38937 en 23 p. application/pdf
spellingShingle DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry
Wang, Ya Wen.
Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title_full Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title_fullStr Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title_full_unstemmed Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title_short Creating openings in vesicle-like polymer nanocavities via templates of nano-scale salt crystals.
title_sort creating openings in vesicle like polymer nanocavities via templates of nano scale salt crystals
topic DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry
url http://hdl.handle.net/10356/38937
work_keys_str_mv AT wangyawen creatingopeningsinvesiclelikepolymernanocavitiesviatemplatesofnanoscalesaltcrystals