Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
Both napthylamine and benzylamine chiral cyclopalladated and cycloplatinated template have been used for monoinsertion of di(phenylethynyl)phenylphosphine ligand into the Pd-C bond of orthopalladated naphthylamine. These insertions proved to be possible under mild reaction conditions and resulted in...
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| Format: | Final Year Project (FYP) |
| Language: | English |
| Published: |
2010
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| Online Access: | http://hdl.handle.net/10356/39827 |