Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions
This thesis describes the asymmetric syntheses of bifunctionalized phosphine complexes, which contain a stereogenic center at phosphorus, through various reactions, including insertion, hydrophosphination, hydration, and hydroamination. Promoted by the coordination of diprop-1-ynylphenylphosphine to...
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| Format: | Thesis |
| Language: | English |
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2010
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| Online Access: | https://hdl.handle.net/10356/41625 |
| _version_ | 1811686047546867712 |
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| author | Luo, Ding |
| author2 | Leung Pak Hing |
| author_facet | Leung Pak Hing Luo, Ding |
| author_sort | Luo, Ding |
| collection | NTU |
| description | This thesis describes the asymmetric syntheses of bifunctionalized phosphine complexes, which contain a stereogenic center at phosphorus, through various reactions, including insertion, hydrophosphination, hydration, and hydroamination. Promoted by the coordination of diprop-1-ynylphenylphosphine to ruthenium, the two alkyne moieties thereafter were functionalized by different reactions, which thus led to the formation of a chiral phosphorous center. This strategy presented is valuable and can be widely used in the synthesis of chiral phosphines. |
| first_indexed | 2024-10-01T04:54:12Z |
| format | Thesis |
| id | ntu-10356/41625 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:54:12Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | ntu-10356/416252023-02-28T23:42:39Z Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions Luo, Ding Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds This thesis describes the asymmetric syntheses of bifunctionalized phosphine complexes, which contain a stereogenic center at phosphorus, through various reactions, including insertion, hydrophosphination, hydration, and hydroamination. Promoted by the coordination of diprop-1-ynylphenylphosphine to ruthenium, the two alkyne moieties thereafter were functionalized by different reactions, which thus led to the formation of a chiral phosphorous center. This strategy presented is valuable and can be widely used in the synthesis of chiral phosphines. DOCTOR OF PHILOSOPHY (SPMS) 2010-07-26T02:47:36Z 2010-07-26T02:47:36Z 2010 2010 Thesis Luo, D. (2010). Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/41625 10.32657/10356/41625 en 297 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Luo, Ding Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title | Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title_full | Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title_fullStr | Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title_full_unstemmed | Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title_short | Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions |
| title_sort | syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination insertion hydration and hydroamination reactions |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/41625 |
| work_keys_str_mv | AT luoding synthesesofbifunctionalizedphosphinecomplexesviarutheniumpromotedstepwisehydrophosphinationinsertionhydrationandhydroaminationreactions |