Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks...
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| Format: | Thesis |
| Language: | English |
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2012
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| Online Access: | https://hdl.handle.net/10356/48065 |
| _version_ | 1826128998966493184 |
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| author | Yin, Peng |
| author2 | Loh Teck Peng |
| author_facet | Loh Teck Peng Yin, Peng |
| author_sort | Yin, Peng |
| collection | NTU |
| description | The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks in organic synthesis, and are also used as starting materials for the synthesis of many compounds such as amino acids, and different alkaloids. Two catalytic systems for the allylic amination with aqueous ammonia and ammonia gas were well-developed. |
| first_indexed | 2024-10-01T07:34:00Z |
| format | Thesis |
| id | ntu-10356/48065 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:34:00Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | ntu-10356/480652023-02-28T23:54:34Z Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines Yin, Peng Loh Teck Peng School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks in organic synthesis, and are also used as starting materials for the synthesis of many compounds such as amino acids, and different alkaloids. Two catalytic systems for the allylic amination with aqueous ammonia and ammonia gas were well-developed. DOCTOR OF PHILOSOPHY (SPMS) 2012-03-01T01:36:45Z 2012-03-01T01:36:45Z 2011 2011 Thesis Yin, P. (2011). Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/48065 10.32657/10356/48065 en 142 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis Yin, Peng Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title | Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title_full | Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title_fullStr | Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title_full_unstemmed | Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title_short | Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| title_sort | part i intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents part ii nhc pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis |
| url | https://hdl.handle.net/10356/48065 |
| work_keys_str_mv | AT yinpeng partiintermolecularhydroaminationbetweennonactivatedalkenesandanilinecatalyzedbylanthanidesaltsinionicsolventspartiinhcpdcomplexcatalyzedallylicaminationusingammoniaforthesynthesisofprimaryamines |